Solution and structural studies of the Cd(II) - Aconitate system

被引：24

作者：

Kostakis, George E. ^{[1
,2
,4
]}

Malandrinos, Gerasimos ^{[1
]}

Nordlander, Ebbe ^{[2
]}

Haukka, Matti ^{[3
]}

Plakatouras, John C. ^{[1
]}

机构：

[1] Univ Ioannina, Dept Chem, GR-45110 Ioannina, Greece

[2] Lund Univ, Inorgan Chem Res Grp, Ctr Chem & Chem Engn, SE-22100 Lund, Sweden

[3] Univ Joensuu, Dept Chem, FIN-80101 Joensuu, Finland

[4] Univ Karlsruhe, Inst Anorgan Chem, D-76131 Karlsruhe, Germany

来源：

POLYHEDRON | 2009年 / 28卷 / 15期

基金：

瑞典研究理事会;

关键词：

Potentiometry; Cadmium complexes; Lewis base; Coordination polymers; Topology; RARE-EARTH-ELEMENTS; CRYSTAL-STRUCTURE; COORDINATION POLYMER; ZINC-COMPLEXES; WATER; ACID; CD;

D O I：

10.1016/j.poly.2009.05.008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexing ability of the binary system trans-aconitic acid (H3L) with regard to Cd(II) and the crystal structures of the binary system Cd(II)-(H3L), [Cd3L2(H2O)(6)] n(1) and ternary systems of Cd(II)-(H3L)-Lewis base [Lewis base = 1,10-phenanthroline (2) and 2,2'-bipyridine (3)] have been determined. Compound I is a rare binodal four-connected three-dimensional (3D) metal-organic framework possessing a moganite (mog) topology. Compounds 2 and 3 represent infinite one-dimensional (1D) chains forming three-dimensional metal-supramolecular structures through H-bond and pi-pi stacking interactions. All compounds have been characterized by spectroscopic and thermogravimetric techniques. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：3227 / 3234

页数：8

共 39 条

[1] One-dimensional Cu(II) coordination polymers: tuning the structure by modulating the "carboxylate arm'' lengths of polycarboxylate ligands [J].