Achieving high performance corrosion and wear resistant epoxy coatings via incorporation of noncovalent functionalized graphene

被引：398

作者：

Chen, Cheng ^{[1
,2
]}

Qiu, Shihui ^{[1
]}

Cui, Mingjun ^{[1
]}

Qin, Songlv ^{[1
]}

Yan, Guoping ^{[2
]}

Zhao, Haichao ^{[1
]}

Wang, Liping ^{[1
]}

Xue, Qunji ^{[1
]}

机构：

[1] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Zhejiang Key Lab Marine Mat & Protect Technol, Key Lab Marine Mat & Related Technol, Ningbo 315201, Zhejiang, Peoples R China

[2] Wuhan Inst Technol, Sch Mat Sci & Engn, Wuhan 430074, Peoples R China

来源：

CARBON | 2017年 / 114卷

关键词：

LITHIUM-ION BATTERIES; CARBON NANOTUBES; COMPOSITES; NANOCOMPOSITES; PROTECTION; DISPERSION; NANOSHEETS; POLYMERS;

D O I：

10.1016/j.carbon.2016.12.044

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Graphene(G)-based polymer nanocomposites have attracted great interest owing to their superior physicochemical properties over polymers. However, the tendency of graphene sheets to aggregate makes it difficult to achieve homogenous dispersion in polymer matrix. Herein, by utilization of poly(2-butylaniline) (P2BA) as a dispersing agent, stable dispersion of graphene in organic solvents was achieved via non-covalent pi-pi interactions between P2BA and graphene nanosheets. The exfoliated graphene nanosheets were then integrated with coating matrix by curing reaction of epoxy resin with P2BA functionalized graphene (P2BA-G) and amine hardener. Embedding a small percentage of well-dispersed graphene nanosheets (P2BA(0.5%)-G(0.5%)) in epoxy coating remarkably improved anticorrosion performance and wear resistance properties, which was attributed to the synergistic effects of the redox catalytic capability of P2BA, high mechanical and barrier properties of well-dispersed graphene nanosheets in the epoxy matrix. The present study provides a promise strategy for development of graphene reinforced organic coatings with superior physical-mechanical properties for metal protection. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：356 / 366

页数：11

共 43 条

[1]

[Anonymous], 2013, EVID-BASED COMPL ALT

[2] Non-covalent functionalization of graphene sheets by sulfonated polyaniline [J].