Dehydrogenation of a tertiary amine-borane by a rhenium complex

被引：19
作者：
Muhammad, Sohail [1 ]
Moncho, Salvador [1 ]
Brothers, Edward N. [1 ]
Bengali, Ashfaq A. [1 ]
机构：
[1] Texas A&M Univ Qatar, Dept Chem, Doha, Qatar
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 44期
关键词：
FREE HYDROGEN-TRANSFER; LEWIS BASE ADDUCTS; TRANSITION-METAL; AMMONIA-BORANE; CATALYZED DEHYDROGENATION; DEHYDROCOUPLING REACTIONS; RUTHENIUM COMPLEXES; HYDRIDE TRANSFER; BOND ACTIVATION; COORDINATION;
D O I：
10.1039/c4cc01771d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Photolysis of CpRe(CO)(3) in the presence of H3BNEt3 yields the trans-CpRe(CO)(2)(H)(2) complex. This preliminary finding presents a rare example of transition metal mediated dehydrogenation of a tertiary amine-borane and suggests that the abstracted hydrogens may be stored in the form of metal hydride complexes.
引用
收藏
页码：5874 / 5877
页数：4
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