Synthesis and reactivity of [Au(NHC)(Bpin)] complexes

被引：24
|
作者：
Zinser, Caroline M. [1 ]
Nahra, Fady [2 ,3 ,4 ]
Falivene, Laura [5 ]
Brill, Marcel [1 ]
Cordes, David B. [1 ]
Slawin, Alexandra M. Z. [1 ]
Cavallo, Luigi [5 ]
Cazin, Catherine S. J. [2 ,3 ]
Nolan, Steven P. [2 ,3 ,6 ]
机构：
[1] Univ St Andrews, EaStCHEM Sch Chem, St Andrews KY16 9ST, Fife, Scotland
[2] Univ Ghent, Dept Chem, Krijgslaan 281 S-3, B-9000 Ghent, Belgium
[3] Univ Ghent, Ctr Sustainable Chem, Krijgslaan 281 S-3, B-9000 Ghent, Belgium
[4] VITO Flemish Inst Technol Res, Separat & Convers Technol, B-2400 Mol, Belgium
[5] King Abdullah Univ Sci & Technol, KCC, Dept KAUST Catalysis Ctr, Thuwal 239556900, Saudi Arabia
[6] King Saud Univ, Coll Sci, Dept Chem, POB 2455, Riyadh 11451, Saudi Arabia
来源：
CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 47期
关键词：
TRANSITION-METAL-COMPLEXES; ALPHA; BETA-UNSATURATED CARBONYL-COMPOUNDS; COPPER(I) BORYL COMPLEXES; SUZUKI-MIYAURA; BORON; COORDINATION; DIBORATION; ACTIVATION; INSERTION; DIBORON;
D O I：
10.1039/c9cc03171e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new class of [Au(NHC)(Bpin)] complexes has been synthesized and their unusual reactivity was investigated using computational and experimental methods. The gold-boryl complexes exhibit unexpected high stability and reactivity.
引用
收藏
页码：6799 / 6802
页数：4
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