Recent advances in the design of magnetic molecules for use as cryogenic magnetic coolants

被引：346

作者：

Liu, Jun-Liang ^{[1
]}

Chen, Yan-Cong ^{[1
]}

Guo, Fu-Sheng ^{[1
]}

Tong, Ming-Liang ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, State Key Lab Optoelect Mat & Technol, Key Lab Bioinorgan & Synthet Chem,Minist Educ, Guangzhou 510275, Guangdong, Peoples R China

来源：

COORDINATION CHEMISTRY REVIEWS | 2014年 / 281卷

基金：

中国国家自然科学基金;

关键词：

d-Block metal; Lanthanide; Magnetic coolant; Magnetocaloric effect; Magnetocaloric material; synthetic strategy; METAL-ORGANIC FRAMEWORK; LOW-TEMPERATURE; WATER-MOLECULES; SPIN-CROSSOVER; GROUND-STATE; CLUSTERS LN; REFRIGERANTS; GD; COOLERS; POLYMERS;

D O I：

10.1016/j.ccr.2014.08.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review outlines recent advances in the design of 3d-, 4f-, and 3d-4f type magnetic molecules for use as excellent cryogenic magnetic coolants based on the magnetocaloric effect (MCE), and the structure-magnetocaloric correlations of reported molecular coolants. Further improvements in the MCE values of molecular magnetic materials are also proposed based on assembly strategies from molecular chemistry and crystal engineering. (C) 2014 Elsevier B.V. All rights reserved.

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收藏

页码：26 / 49

页数：24

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