1D/2D Carbon Nanomaterial-Polymer Dielectric Composites with High Permittivity for Power Energy Storage Applications

被引:442
作者
Dang, Zhi-Min [1 ,2 ]
Zheng, Ming-Sheng [2 ]
Zha, Jun-Wei [2 ]
机构
[1] Tsinghua Univ, Dept Elect Engn, State Key Lab Power Syst, Beijing 100084, Peoples R China
[2] Beijing Univ Sci & Technol, Dept Polymer Sci & Engn, Beijing 100083, Peoples R China
基金
中国国家自然科学基金;
关键词
carbon nanomaterials; polymer composites; dielectric properties; breakdown strength; energy storage; REDUCED GRAPHENE OXIDE; MECHANICAL-PROPERTIES; BARIUM-TITANATE; FILLED POLYMER; NANOCOMPOSITES; NANOTUBES; CONSTANT; BEHAVIOR; PERFORMANCE; FABRICATION;
D O I
10.1002/smll.201503193
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
With the development of flexible electronic devices and large-scale energy storage technologies, functional polymer-matrix nanocomposites with high permittivity (high-k) are attracting more attention due to their ease of processing, flexibility, and low cost. The percolation effect is often used to explain the high-k characteristic of polymer composites when the conducting functional fillers are dispersed into polymers, which gives the polymer composite excellent flexibility due to the very low loading of fillers. Carbon nanotubes (CNTs) and graphene nanosheets (GNs), as one-dimensional (1D) and two-dimensional (2D) carbon nanomaterials respectively, have great potential for realizing flexible high-k dielectric nanocomposites. They are becoming more attractive for many fields, owing to their unique and excellent advantages. The progress in dielectric fields by using 1D/2D carbon nanomaterials as functional fillers in polymer composites is introduced, and the methods and mechanisms for improving dielectric properties, breakdown strength and energy storage density of their dielectric nanocomposites are examined. Achieving a uniform dispersion state of carbon nanomaterials and preventing the development of conductive networks in their polymer composites are the two main issues that still need to be solved in dielectric fields for power energy storage. Recent findings, current problems, and future perspectives are summarized.
引用
收藏
页码:1688 / 1701
页数:14
相关论文
共 97 条
[1]   Polymer Composite and Nanocomposite Dielectric Materials for Pulse Power Energy Storage [J].
Barber, Peter ;
Balasubramanian, Shiva ;
Anguchamy, Yogesh ;
Gong, Shushan ;
Wibowo, Arief ;
Gao, Hongsheng ;
Ploehn, Harry J. ;
zur Loye, Hans-Conrad .
MATERIALS, 2009, 2 (04) :1697-1733
[2]   The effect of nanotube surface oxidation on the electrical properties of multiwall carbon nanotube/poly(vinylidene fluoride) composites [J].
Carabineiro, S. A. C. ;
Pereira, M. F. R. ;
Nunes-Pereira, J. ;
Silva, J. ;
Caparros, C. ;
Sencadas, V. ;
Lanceros-Mendez, S. .
JOURNAL OF MATERIALS SCIENCE, 2012, 47 (23) :8103-8111
[3]   Electrical and Piezoelectric Behavior of Polyamide/PZT/CNT Multifunctional Nanocomposites [J].
Carponcin, Delphine ;
Dantras, Eric ;
Dandurand, Jany ;
Aridon, Gwenaelle ;
Levallois, Franck ;
Cadiergues, Laurent ;
Lacabanne, Colette .
ADVANCED ENGINEERING MATERIALS, 2014, 16 (08) :1018-1025
[4]  
CHAN NH, 1984, J AM CERAM SOC, V67, P285, DOI 10.1111/j.1151-2916.1984.tb18849.x
[5]   The production of carbon nanotube/epoxy composites with a very high dielectric constant and low dielectric loss by microwave curing [J].
Chang, Jianfei ;
Liang, Guozheng ;
Gu, Aijuan ;
Cai, Shiduan ;
Yuan, Li .
CARBON, 2012, 50 (02) :689-698
[6]   Ultra high permittivity and significantly enhanced electric field induced strain in PEDOT:PSS-RGO@PU intelligent shape-changing electro-active polymers [J].
Chen, Tian ;
Qiu, Jinhao ;
Zhu, Kongjun ;
Li, Jinhuan ;
Wang, Jingwen ;
Li, Shuqin ;
Wang, Xiaoliang .
RSC ADVANCES, 2014, 4 (109) :64061-64067
[7]   Enhanced dielectric properties of amino-modified-CNT/polyimide composite films with a sandwich structure [J].
Chen, Yaqin ;
Lin, Baoping ;
Zhang, Xueqin ;
Wang, Junchuan ;
Lai, Changwei ;
Sun, Ying ;
Liu, Yurong ;
Yang, Hong .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (34) :14118-14126
[8]  
Cho S., 2015, ACS APPL MAT INTERFA
[9]   Porous graphene sandwich/poly(vinylidene fluoride) composites with high dielectric properties [J].
Chu, Liangyong ;
Xue, Qingzhong ;
Sun, Jin ;
Xia, Fujun ;
Xing, Wei ;
Xia, Dan ;
Dong, Mingdong .
COMPOSITES SCIENCE AND TECHNOLOGY, 2013, 86 :70-75
[10]   Small but strong: A review of the mechanical properties of carbon nanotube-polymer composites [J].
Coleman, Jonathan N. ;
Khan, Umar ;
Blau, Werner J. ;
Gun'ko, Yurii K. .
CARBON, 2006, 44 (09) :1624-1652