Synthesis of Symmetrical and Non-symmetrical Diimines from Dimedone

被引:3
|
作者
Saeed, Bahjat A. [1 ]
Musad, Ibrahim A. [1 ]
机构
[1] Univ Basrah, Coll Educ, Dept Chem, Basrah, Iraq
来源
MOLECULES | 2009年 / 14卷 / 06期
关键词
dimedone; diimines; enaminothiones; B3LYP/6-31G(d; p); CHEMISTRY;
D O I
10.3390/molecules14062278
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Symmetrical and non-symmetrical diimines derived from dimedone were synthesized by the reaction of their corresponding enaminothiones with primary amines. The synthesized compounds were characterized using micro analytical data and NMR spectroscopy. Theoretical calculations by B3LYP/6-31G(d,p) level of theory show that the enolic form is the most stable within the possible tautomeric forms of the compounds.
引用
收藏
页码:2278 / 2285
页数:8
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