Crystal structure analyses of bis(triphenylphosphoranyliden)ammonium bis(pentafluoroethyl) argentate, [Ph3P=N=PPh3][Ag(C2F5)2] and bis[bis(triphenylphosphoranyliden)ammonium] tetrachloro-diargentate, [Ph3P=N=PPh3]2[ClAg(μ-Cl)2AgCl]

被引：10

作者：

Aboulkacem, Said ^{[1
]}

Tyrra, Wieland ^{[1
]}

Pantenburg, Ingo ^{[1
]}

机构：

[1] Univ Cologne, Inst Anorgan Chem, D-50939 Cologne, Germany

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2006年 / 36卷 / 02期

关键词：

bis(pentafluoroethyl)argentate(I); tetrachlorodiargentate(I);

D O I：

10.1007/s10870-005-9035-7

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Bis(triphenylphosphoranyliden)ammonium bis(pentafluoroethyl)argentate, [Ph3P=N= PPh3][Ag(C2F5)(2)] (1) and bis[bis(triphenylphosphoranyliden)ammonium]tetrachloro-diargentate, [Ph3P=N=PPh3](2)[ClAg(mu-Cl)(2)AgCl] (2) were crystallized from the reaction mixture of pentafluoroethylsilver(I) and bis(triphenylphosphoranyliden)ammonium chlo-ride. Crystallization of 1 occurs in the centrosymmetric monoclinic space group P2(1)/c (No. 14) with a = 17.083(2) angstrom, b = 11.600(2) angstrom, c = 19.833(2) angstrom, beta = 109.66(1)degrees, V = 3700.8(7) angstrom(3), Z = 4. 2 crystallizes in the centrosymmetric orthorhombic space group Pbca (No. 61) with a = 19.540(1) angstrom, b = 15.926(1) angstrom, c = 20.160(1) angstrom, V = 6273.6(3) angstrom(3), Z = 8.

引用

页码：141 / 145

页数：5