Low-humidity sensing properties of carboxylic acid functionalized carbon nanomaterials measured by a quartz crystal microbalance

被引：21
作者：
Su, Pi-Guey [1 ]
Kuo, Xian-Ren [1 ]
机构：
[1] Chinese Culture Univ, Dept Chem, Taipei 111, Taiwan
来源：
SENSORS AND ACTUATORS A-PHYSICAL | 2014年 / 205卷
关键词：
Low-humidity sensing; Quartz crystal microbalance; MWCNT-COOH; GO; Adsorption dynamic analysis; FIELD-EFFECT TRANSISTORS; RELATIVE-HUMIDITY; COMPOSITE-MATERIAL; GRAPHENE OXIDE; THIN-FILMS; SENSOR; NANOTUBES;
D O I：
10.1016/j.sna.2013.10.024
中图分类号：
TM [电工技术]; TN [电子技术、通信技术];
学科分类号：
0808 ; 0809 ;
摘要：
Low-humidity sensing performance of raw multi-walled nanotubes (MWCNTs),graphene and carboxylic acid functionalized MWCNTs (MWCNT-COOH) and graphene (GO) thin films were investigated by using a quartz crystal microbalance (QCM). The characterizations of the thin films were analyzed by scanning electron microscopy (SEM) and atomic force microscopy (AFM). Water vapor molecules adsorbed onto the GO thin film had a larger frequency shift than the MWCNT-COOH thin film (especially at low humidity levels). Adsorption dynamic analysis, molecular mechanics calculation (association constant), was applied to elucidate how amounts of surface functionalized groups (-COOH) of MWCNTs and graphene increase the sensitivity to low-humidity. (C) 2013 Elsevier B.V. All rights reserved.
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收藏
页码：126 / 132
页数：7
相关论文
共 36 条
[1]   The application of CNT/Nafion composite material to low humidity sensing measurement [J].
Chen, HW ;
Wu, RJ ;
Chan, KH ;
Sun, YL ;
Su, PG .
SENSORS AND ACTUATORS B-CHEMICAL, 2005, 104 (01) :80-84
[2]  
Cunningham A.J., 1998, INTRO BIOANALYTICAL, P307
[3]  
Delannoy F.P., 2000, SENSOR ACTUAT B-CHEM, V84, P285
[4]   Two-beam-laser interference mediated reduction, patterning and nanostructuring of graphene oxide for the production of a flexible humidity sensing device [J].
Guo, Li ;
Jiang, Hao-Bo ;
Shao, Rui-Qiang ;
Zhang, Yong-Lai ;
Xie, Sheng-Yi ;
Wang, Jian-Nan ;
Li, Xian-Bin ;
Jiang, Fan ;
Chen, Qi-Dai ;
Zhang, Tong ;
Sun, Hong-Bo .
CARBON, 2012, 50 (04) :1667-1673
[5]   The synthesis, characterization of oxidized multi-walled carbon nanotubes, and application to surface acoustic wave quartz crystal gas sensor [J].
Hsu, Hao-Lin ;
Jehng, Hh-Mirn ;
Sung, Yuh ;
Wang, Li-Chun ;
Yang, Sang-Ren .
MATERIALS CHEMISTRY AND PHYSICS, 2008, 109 (01) :148-155
[6]   Synthesis of defect graphene and its application for room temperature humidity sensing [J].
Huang, Qingwu ;
Zeng, Dawen ;
Tian, Shouqin ;
Xie, Changsheng .
MATERIALS LETTERS, 2012, 83 :76-79
[7]   HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].
IIJIMA, S .
NATURE, 1991, 354 (6348) :56-58
[8]   A hydrogen storage mechanism in single-walled carbon nanotubes [J].
Lee, SM ;
An, KH ;
Lee, YH ;
Seifert, G ;
Frauenheim, T .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (21) :5059-5063
[9]   Humidity sensitive field effect transistors [J].
Lee, SP ;
Park, KJ .
SENSORS AND ACTUATORS B-CHEMICAL, 1996, 35 (1-3) :80-84
[10]   Nanosized zeolite films for vapor-sensing applications [J].
Mintova, S ;
Bein, T .
MICROPOROUS AND MESOPOROUS MATERIALS, 2001, 50 (2-3) :159-166
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