Synthesis, characterization and thermal study of CoSb2 semiconductor by mechanical alloying

被引：5

作者：

Amornpitoksuk, P. ^{[1
]}

Suwanboon, S. ^{[2
]}

机构：

[1] Prince Songkla Univ, Fac Sci, Dept Chem, Hat Yai 90112, Songkhla, Thailand

[2] Prince Songkla Univ, Fac Sci, Mat Sci Program, Hat Yai 90112, Songkhla, Thailand

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2009年 / 473卷 / 1-2期

关键词：

Mechanical alloying; Amorphous materials;

D O I：

10.1016/j.jallcom.2008.05.098

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A nanocrystalline CoSb2 crystallizing in arsenopyrite structure was synthesized by mechanical alloying from elemental Co and Sb powders. The samples with different times were characterized by X-ray diffraction spectroscopy (XRD) and scanning electron microscopy (SEM). The synthesized powder shows arsenopyrite structure completely after 30h of milling. The crystallite size is decreased with increasing milling time. At 60 h of milling, the sample shows a peritectic decomposition at 935.41 degrees C as the arsenopyrite structure transforms to marcasite structure. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：373 / 375

页数：3

共 7 条

[1]

AMORNPITOKSUK P, J ALLOYS CO IN PRESS

[2] Preparation and thermoelectric properties of IrxCo1-xSb2 alloys [J].