Comparison of hydrogen storage properties of pure Mg and milled pure Mg

被引:21
作者
Song, Myoung Youp [1 ]
Kwak, Young Jun [2 ]
Lee, Seong Ho [2 ]
Park, Hye Ryoung [3 ]
机构
[1] Chonbuk Natl Univ, Engn Res Inst, Hydrogen & Fuel Cell Res Ctr, Div Adv Mat Engn, Jeonju 561756, South Korea
[2] Chonbuk Natl Univ, Grad Sch, Dept Mat Engn, Jeonju 561756, South Korea
[3] Chonnam Natl Univ, Sch Appl Chem Engn, Kwangju 500757, South Korea
关键词
Hydrogen absorbing materials; pure magnesium; mechanical alloying/milling; microstructure; X-ray diffraction; RAPID SOLIDIFICATION; ALLOYS; MAGNESIUM; KINETICS; HYDRIDE; NI; IMPROVEMENT; NICKEL; OXIDE; TI;
D O I
10.1007/s12034-014-0013-6
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Hydrogen storage properties of pure Mg were studied at 593 K under 12 bar H-2. In order to increase the hydriding and dehydriding rates, pure Mg was ground under hydrogen atmosphere (reactive mechanical grinding, RMG) and its hydrogen storage properties were subsequently investigated. Pure Mg absorbed hydrogen very slowly. At the number of cycles (n) of 1, pure Mg absorbed 0-05 wt% H for 5 min, 0.08 wt% H for 10 min and 0.29 wt% H for 60 min at 593 K under 12 bar H-2. Activation was completed at the fifth cycle. At n = 6, pure Mg absorbed 1.76 wt% H for 5 min, 2.17 wt% H for 10 min and 3.40 wt% H for 60 min. The activation of pure Mg after RMG was completed at the sixth cycle. At n = 7, pure Mg after RMG absorbed 2.57 wt% H for 5 min, 3.21 wt% H for 10 min and 4.15 wt% H for 60 min.
引用
收藏
页码:831 / 835
页数:5
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