Generalized Fluctuation-Dissipation Theorem for Non-equilibrium Spatially Extended Systems

The fluctuation-dissipation theorem (FDT) connecting the response of the system to external perturbations with the fluctuations at thermodynamic equilibrium is a central result in statistical physics. There has been effort devoted to extending the FDT in several different directions since its original formulation. In this work we establish a generalized form of the FDT for spatially extended non-equilibrium stochastic systems described by continuous fields. The generalized FDT is formulated with the aid of the non-equilibrium force decomposition in the potential landscape and flux field theoretical framework. The general results are substantiated in the setting of the Ornstein-Uhlenbeck (OU) process and further illustrated by a more specific example worked out in detail. The key feature of this generalized FDT for non-equilibrium spatially extended systems is that it represents a ternary relation rather than a binary relation as the FDT for equilibrium systems does. In addition to the response function and the time derivative of the field-field correlation function that are present in the equilibrium FDT, the field-flux correlation function also enters the generalized FDT. This additional contribution originates from detailed balance breaking that signifies the non-equilibrium irreversible nature of the steady state. In the special case when the steady state is an equilibrium state obeying detailed balance, the field-flux correlation function vanishes and the ternary relation in the generalized FDT reduces to the binary relation in the equilibrium FDT.