A Spin-Crossover Cluster of Iron(II) Exhibiting a Mixed-Spin Structure and Synergy between Spin Transition and Magnetic Interaction

被引：175

作者：

Wu, Da-Yu ^{[1
,2
,3
]}

Sato, Osamu ^{[1
]}

Einaga, Yasuaki ^{[4
]}

Duan, Chun-Ying ^{[3
]}

机构：

[1] Kyushu Univ, Inst Mat Chem & Engn, Fukuoka 8168580, Japan

[2] Anqing Normal Univ, Sch Chem & Chem Engn, Anhui Key Lab Funct Coordinat Chem, Anqing 246011, Peoples R China

[3] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing, Peoples R China

[4] Keio Univ, Fac Sci & Technol, Dept Chem, Yokohama, Kanagawa 2238522, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 08期

关键词：

cluster compounds; iron; magnetic properties; spin crossover; COORDINATION POLYMER; THERMAL HYSTERESIS; CRYSTAL-STRUCTURE; DINUCLEAR; COMPLEX; TEMPERATURE; PRESSURE; STATE; SUSCEPTIBILITY; MONONUCLEAR;

D O I：

10.1002/anie.200804529

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

How low can you go? An Fell4 square was prepared by self-assembly and exhibits both thermally induced and photoinduced spin crossover from a system with four high-spin (HS) centers to one with two high-spin and two low-spin (LS) centres. The spin-crossover sites are located on the same side of the square, and the spin transition and magnetic interactions (see picture) are synergistically coupled. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1475 / 1478

页数：4

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