Synthesis and characterization of noncentrosymmetric main chain hydrogen bonded macromolecules incorporating an azo-stilbazole acceptor

被引：1

作者：

Dyer, Daniel J. ^{[1
]}

Wolf, Jeremy R. ^{[1
,2
]}

机构：

[1] So Illinois Univ, Dept Chem, Carbondale, IL 62901 USA

[2] ABC Labs, Columbia, MO 65202 USA

来源：

MACROMOLECULAR RESEARCH | 2014年 / 22卷 / 08期

基金：

美国国家科学基金会;

关键词：

hydrogen bonded macromolecules; azo-stilbazole; POLYMER ELECTRETS; CRYSTAL-STRUCTURE; LIQUID-CRYSTALS; AZOBENZENE; STILBENE; DESIGN; SERIES;

D O I：

10.1007/s13233-014-2105-y

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The syntheses and characterization of three noncentrosymmetric main chain hydrogen bonded macromolecules which incorporate diethyl-[4-(pyridin-4-ylazo)-phenyl]-amine hydrogen bond acceptor units are reported. These macromolecules participate in strong intermolecular hydrogen bonding as demonstrated using attenuated total reflectance (ATR) FTIR. The phase transitions of these macromolecules depend on the identity of the hydrogen bond donor. Mixtures of these azo-stilbazole macromolecules with noncentrosymmetric hydrogen bonded liquid crystalline macromolecules possess nematic liquid crystalline phases when the concentration of the azo-stilbazole macromolecule is a parts per thousand currency sign 50 mol%.

引用

页码：870 / 874

页数：5

共 31 条

[1] Self-assembly of amphoteric azopyridine carboxylic acids: Organized structures and macroscopic organized morphology influenced by heat, pH change, and light [J].

Aoki, K ;

Nakagawa, M ;

Ichimura, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (44) :10997-11004

[2]

Baldwin G., 1969, INTRO NONLINEAR OPTI

[3]

Bloor D, 1991, ORGANIC MAT NONLINEA

[4] A REFINEMENT OF CRYSTAL STRUCTURE OF AZOBENZENE [J].

BROWN, CJ .

ACTA CRYSTALLOGRAPHICA, 1966, 21 :146-&

[5]

Brown P. E., 1990, J CHEM SOC P1, V11, P2979

[6]

Butcher PN., 1990, Cambridge Studies in Modern Optics, DOI 10.1017/CBO9781139167994

[7] INDUSTRIAL APPLICATIONS OF PIEZOELECTRIC POLYMER TRANSDUCERS [J].

CHEN, QX ;

PAYNE, PA .

MEASUREMENT SCIENCE AND TECHNOLOGY, 1995, 6 (03) :249-267

[8] Design and synthesis of a novel and potent series of inhibitors of cytosolic phospholipase A2 based on a 1,3-disubstituted propan-2-one skeleton [J].

Connolly, S ;

Bennion, C ;

Botterell, S ;

Croshaw, PJ ;

Hallam, C ;

Hardy, K ;

Hartopp, P ;

Jackson, CG ;

King, SJ ;

Lawrence, L ;

Mete, A ;

Murray, D ;

Robinson, DH ;

Smith, GM ;

Stein, L ;

Walters, I ;

Wells, E ;

Withnall, WJ .

JOURNAL OF MEDICINAL CHEMISTRY, 2002, 45 (06) :1348-1362

[9]

DYER DJ, 2003, POLYM PREPRINTS, V44, P713

[10]

DYER DJ, 2003, POLYM PREPR, V44, P578

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