Mixed-ligand ruthenium(III) complexes with acetylacetonates

被引：0

作者：

Gupta, AK ^{[1
]}

Poddar, RK ^{[1
]}

机构：

[1] NE Hill Univ, Dept Chem, Shillong 793003, Meghalaya, India

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 1999年 / 38卷 / 12期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Synthesis of [Ru(acac)(2)(CH3CN)(1)]ClO4 has been achieved by an oxidation of [Ru(acac)(2)(CH3CN)(2)] with AgClO4 or a Ce(IV) salt. The complex [Ru(acac)(2)L-2]ClO4 [ where L = py, 3Me-py, 4Me-py, PPh3, AsPh3, 3,5-dimethylpyrazole(dmpzH), imidazole(Im), or benzimidazole(BzIm), L-2= 2,2'-bipyridine(bipy) or 1,10-phenanthroline(phen)] has been synthesized either by the displacement of CH3CN in [Ru(acac)(2)(CH3CN)(2)]ClO4 by L or L-2 or by the oxidation of [Ru(acac)(2)L-2] using AgClO4 or 3 Ce(IV) salt and characterized using elemental analyses, magnetic and conductivity data, IR, UV-visible, H-1 NMR and ESR spectral data and cyclic voltammetric studies.

引用

页码：1228 / 1231

页数：4

共 50 条

[1] MIXED-LIGAND COMPLEXES OF RUTHENIUM(III)EDTA WITH PYRIMIDINES
KHAN, BT
ANNAPOORNA, K
INORGANICA CHIMICA ACTA, 1990, 171 (02) : 157 - 163
[2] MIXED-LIGAND COMPLEXES OF RUTHENIUM(III)EDTA WITH NUCLEOSIDES
KHAN, BT
ANNAPOORNA, K
POLYHEDRON, 1991, 10 (20-21) : 2465 - 2470
[3] STUDIES ON MIXED-LIGAND COMPLEXES OF RUTHENIUM(III) EDTA WITH PURINES
KHAN, BT
ANNAPOORNA, K
INORGANICA CHIMICA ACTA, 1990, 176 (02) : 241 - 246
[4] MIXED-LIGAND COMPLEXES OF CHROMIUM(III) AND RUTHENIUM(III) IONS WITH IMIDES AND AMINES
ISLAM, MS
UDDIN, MM
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1992, 22 (09): : 1303 - 1315
[5] Mixed-ligand Complexes of Ruthenium(II) and Iridium(III) with Triphenylphosphine and Thiocarbohydrazide
Pandey, R. N.
Gautam, K. V.
ASIAN JOURNAL OF CHEMISTRY, 2011, 23 (10) : 4517 - 4519
[6] STUDIES ON MIXED-LIGAND COMPLEXES OF RUTHENIUM(III)EDTA WITH NUCLEOTIDES AND PHOSPHATES
ANNAPOORNA, K
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 203 : 62 - INOR
[7] MIXED-LIGAND COMPLEXES OF RUTHENIUM(III) AND RUTHENIUM(II) WITH ETHYLENEDIAMINETETRAACETATE AND BIDENTATE PHOSPHINES AND ARSINES
KHAN, MMT
VENKATASUBRAMANIAN, K
SHIRIN, Z
BHADBHADE, MM
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (05): : 885 - 890
[8] Synthesis and characterization of mixed-ligand ruthenium(III) complexes with oxalate and acetylacetonate ions
Hoshino, Y
Eto, M
Fujino, T
Yukawa, Y
Ohta, T
Endo, A
Shimizu, K
Satô, GP
INORGANICA CHIMICA ACTA, 2004, 357 (02) : 600 - 604
[9] SOME MIXED-LIGAND HYDRIDOCARBONYL AND HYDRIDOPHOSPHINE COMPLEXES OF RUTHENIUM(II) AND IRIDIUM(III)
PANDEY, RN
KUMAR, S
KUMAR, A
KUMAR, SK
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1993, 70 (06) : 495 - 498
[10] MIXED-LIGAND COMPLEXES OF COBALT(III)
DEY, K
DE, RL
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1973, 402 (01): : 120 - 128

← 1 2 3 4 5 →