Palladium-catalyzed regio- and diastereoselective allylic alkylation with azlactones using triphenylarsine

被引：17

作者：

Kawatsura, Motoi ^{[1
]}

Ikeda, Daiji

Ishii, Tamiko

Komatsu, Yuji

Uenishi, Junichi

机构：

[1] Tottori Univ, Fac Engn, Dept Mat Sci, Tottori 6808552, Japan

[2] Kyoto Pharmaceut Univ, Kyoto 6078412, Japan

来源：

SYNLETT | 2006年 / 15期

关键词：

palladium catalysis; triphenylarsine; regioselectivity; diastereoselectivity; alkylations;

D O I：

10.1055/s-2006-950400

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The palladium-catalyzed regio- and diastereoselective allylic alkylation of (R)-2-acetoxy-4-phenyl-3-butene with azlactones using AsPh3 successfully occurred. The stereochemistries were highly controlled, and the reaction produced a coupling product which possessed vicinal chiral quaternary and tertiary carbon centers.

引用

页码：2435 / 2438

页数：4

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