Preparation of phosphines through C-P bond formation

被引：167

作者：

Wauters, Iris ^{[1
]}

Debrouwer, Wouter ^{[1
]}

Stevens, Christian V. ^{[1
]}

机构：

[1] Univ Ghent, Fac Biosci Engn, Dept Sustainable Organ Chem & Technol, Res Grp SynBioC, B-9000 Ghent, Belgium

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 10卷

关键词：

cross-coupling; enantioselectivity; hydrophosphination; organophosphorus chemistry; phosphines; phosphine-boranes; substitution reactions; trivalent phosphorus; PALLADIUM-CATALYZED PHOSPHINATION; CROSS-COUPLING REACTIONS; WATER-SOLUBLE PHOSPHINES; FREE-RADICAL ADDITION; ORGANOCATALYTIC ASYMMETRIC HYDROPHOSPHINATION; BULKY END CAPS; SECONDARY PHOSPHINES; ENANTIOSELECTIVE SYNTHESIS; CHIRAL PHOSPHINE; INTERMOLECULAR HYDROPHOSPHINATION;

D O I：

10.3762/bjoc.10.106

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Phosphines are an important class of ligands in the field of metal-catalysis. This has spurred the development of new routes toward functionalized phosphines. Some of the most important C-P bond formation strategies were reviewed and organized according to the hybridization of carbon in the newly formed C-P bond.

引用

页码：1064 / 1096

页数：33

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