Synthesis of ruthenium (II) complexes containing a dihydroperimidine-derived phosphine ligand and their application in transfer hydrogenation of ketones

被引：15

作者：

Fu, Qi ^{[1
]}

Zhang, Lei ^{[1
]}

Yi, Tao ^{[1
]}

Zou, Mingjun ^{[1
]}

Wang, Xiaoyan ^{[1
]}

Fu, Haiyan ^{[1
]}

Li, Ruixiang ^{[1
]}

Chen, Hua ^{[1
]}

机构：

[1] Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Sichuan, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 38卷

基金：

中国国家自然科学基金;

关键词：

Ruthenium; Phosphine; Transfer hydrogenation; Ketone; ASYMMETRIC TRANSFER HYDROGENATION; CATALYZED TRANSFER HYDROGENATION; CARBONYL-COMPOUNDS; CHIRAL LIGANDS; BEARING; REDUCTION;

D O I：

10.1016/j.inoche.2013.10.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new ruthenium (II) phosphine complexes (eta(6)-C6H6)RuCl2[mu- (PPh2CH2N)(2)CH2(C10H6)]RuCl2(eta(6)-C6H6) (1) and RuCl2(PPh3)[(PPh2CH2N)(2)CH2(C10H6)] (2) were synthesized and characterized by H-1 NMR, P-31 {H-1) NMR and elemental analysis. Moreover, the structure of ruthenium (II) phosphine complex 1 was confirmed by X-ray crystallography. With complex 1 as the catalyst, the transfer hydrogenation of ketones reacted well, affording the corresponding alcohols in good yields under mild conditions. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：28 / 32

页数：5

共 29 条

[1] Ruthenium Complexes of CP3: A New Carbon-Centered Polydentate Podand Ligand [J].

Allen, Olivia R. ;

Field, Leslie D. ;

Magill, Alison M. ;

Vuong, Khuong Q. ;

Bhadbhade, Mohan M. ;

Dalgarno, Scott J. .

ORGANOMETALLICS, 2011, 30 (23) :6433-6440

[2] The first Ru(η3-PCP) complexes of the electron-rich pincer ligand 1,3-bis((dicyclohexylphosphino)methyl)benzene:: Structure and mechanism in transfer hydrogenation catalysis [J].

Amoroso, D ;

Jabri, A ;

Yap, GPA ;

Gusev, DG ;

dos Santos, EN ;

Fogg, DE .

ORGANOMETALLICS, 2004, 23 (17) :4047-4054

[3] Applications of transition metal complexes containing 3,3′-bis(diphenylphosphinoamine)-2,2′-bipyridine ligand to transfer hydrogenation of ketones [J].

Aydemir, Murat ;

Meric, Nermin ;

Baysal, Akin .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2012, 720 :38-45

[4] A modular design of metal catalysts for the transfer hydrogenation of aromatic ketones [J].

Aydemir, Murat ;

Baysal, Akin ;

Gumgum, Bahattin .

APPLIED ORGANOMETALLIC CHEMISTRY, 2012, 26 (01) :1-8

[5] Ruthenium-catalyzed transfer hydrogenation of aromatic ketones with aminophosphine or bis(phosphino)amine ligands derived from isopropyl substituted anilines [J].

Aydemir, Murat ;

Baysal, Akin .

POLYHEDRON, 2010, 29 (04) :1219-1224

[6] Fluorous derivatives of (1R,2R)-diaminocyclohexane as chiral ligands for metal-catalyzed asymmetric reactions [J].

Bayardon, J ;

Sinou, D ;

Holczknecht, O ;

Mercs, L ;

Pozzi, G .

TETRAHEDRON-ASYMMETRY, 2005, 16 (13) :2319-2327

[7] CATALYTIC TRANSFER HYDROGENATION [J].

BRIEGER, G ;

NESTRICK, TJ .

CHEMICAL REVIEWS, 1974, 74 (05) :567-580

[8] Ketone transfer hydrogenation reactions catalyzed by a phosphinite ruthenium PCP complex -: The X-ray crystal structure of [C6H4-1,3-(OPPh2{Ru(η6-p-cymene)Cl2}2](η6-p-cymene)Cl2}2] [J].

Cerón-Camacho, RC ;

Gómez-Benítez, V ;

Le Lagadec, R ;

Morales-Morales, D ;

Toscano, RA .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 247 (1-2) :124-129

[9] Mechanisms of the H2-hydrogenation and transfer hydrogenation of polar bonds catalyzed by ruthenium hydride complexes [J].

Clapham, SE ;

Hadzovic, A ;

Morris, RH .

COORDINATION CHEMISTRY REVIEWS, 2004, 248 (21-24) :2201-2237

[10] Rutheuium(II)-catalyzed asymmetric transfer hydrogenation of carbonyl compounds with 2-propanol and ephedrine-type ligands [J].

Everaere, K ;

Mortreux, A ;

Carpentier, JF .

ADVANCED SYNTHESIS & CATALYSIS, 2003, 345 (1-2) :67-77

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