Facile microwave synthesis of CoFe2O4 spheres and their application as an anode for lithium-ion batteries

被引:20
作者
Yoon, Sukeun [1 ]
机构
[1] Kongju Natl Univ, Div Adv Mat Engn, Chungnam 330717, South Korea
关键词
Lithium-ion batteries; Anode; CoFe2O4; Microwave-hydrothermal reaction; HIGH-PERFORMANCE ANODES; OXIDE COMPOSITE; STORAGE;
D O I
10.1007/s10800-014-0716-9
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
CoFe2O4 spheres were synthesized using a microwave-hydrothermal reaction and characterized by X-ray diffraction, electron microscopy, and electrochemical analysis. This simple synthesis method led to a uniform dispersion of nanosized building blocks in the spheres, which exhibit significantly improved cycling performance and rate capability in lithium cells. The excellent electrochemical performances of CoFe2O4 sphere are attributed to an increased lithium wetting property at the electrode-electrolyte interface, facile lithium-ion diffusion, and better alleviation of the structure pulverization during charge-discharge process.
引用
收藏
页码:1069 / 1074
页数:6
相关论文
共 30 条
[1]   Nanomaterials for rechargeable lithium batteries [J].
Bruce, Peter G. ;
Scrosati, Bruno ;
Tarascon, Jean-Marie .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (16) :2930-2946
[2]   Crumpled Graphene-Molybdenum Oxide Composite Powders: Preparation and Application in Lithium-Ion Batteries [J].
Choi, Seung Ho ;
Kang, Yun Chan .
CHEMSUSCHEM, 2014, 7 (02) :523-528
[3]   Ordered porous materials for emerging applications [J].
Davis, ME .
NATURE, 2002, 417 (6891) :813-821
[4]   Direct synthesis of iron oxide nanoparticles on an iron current collector as binder-free anode materials for lithium-ion batteries [J].
Ding, Yunhai ;
Li, Jiaxin ;
Zhao, Yi ;
Guan, Lunhui .
MATERIALS LETTERS, 2012, 81 :105-107
[5]   Synthesis of porous CoFe2O4 octahedral structures and studies on electrochemical Li storage behavior [J].
Fu, Xinning ;
Chen, Dan ;
Wang, Min ;
Yang, Yushi ;
Wu, Qingzhi ;
Ma, Jianmin ;
Zhao, Xinsheng .
ELECTROCHIMICA ACTA, 2014, 116 :164-169
[6]   On the microporous nature of mesoporous molecular sieves [J].
Göltner, CG ;
Smarsly, B ;
Berton, B ;
Antonietti, M .
CHEMISTRY OF MATERIALS, 2001, 13 (05) :1617-1624
[7]   Growth of nanowire superlattice structures for nanoscale photonics and electronics [J].
Gudiksen, MS ;
Lauhon, LJ ;
Wang, J ;
Smith, DC ;
Lieber, CM .
NATURE, 2002, 415 (6872) :617-620
[8]   CoFe2O4 and NiFe2O4 synthesized by sol-gel procedures for their use as anode materials for Li ion batteries [J].
Lavela, P. ;
Tirado, J. L. .
JOURNAL OF POWER SOURCES, 2007, 172 (01) :379-387
[9]   Self-Assembled Fe3O4 Nanoparticle Clusters as High-Performance Anodes for Lithium Ion Batteries via Geometric Confinement [J].
Lee, Soo Hong ;
Yu, Seung-Ho ;
Lee, Ji Eun ;
Jin, Aihua ;
Lee, Dong Jun ;
Lee, Nohyun ;
Jo, Hyungyung ;
Shin, Kwangsoo ;
Ahn, Tae-Young ;
Kim, Young-Woon ;
Choe, Heeman ;
Sung, Yung-Eun ;
Hyeon, Taeghwan .
NANO LETTERS, 2013, 13 (09) :4249-4256
[10]   Confined Nanospace Pyrolysis for the Fabrication of Coaxial Fe3O4@C Hollow Particles with a Penetrated Mesochannel as a Superior Anode for Li-Ion Batteries [J].
Lei, Cheng ;
Han, Fei ;
Sun, Qiang ;
Li, Wen-Cui ;
Lu, An-Hui .
CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (01) :139-145