Facile microwave synthesis of CoFe2O4 spheres and their application as an anode for lithium-ion batteries

被引:20
作者
Yoon, Sukeun [1 ]
机构
[1] Kongju Natl Univ, Div Adv Mat Engn, Chungnam 330717, South Korea
关键词
Lithium-ion batteries; Anode; CoFe2O4; Microwave-hydrothermal reaction; HIGH-PERFORMANCE ANODES; OXIDE COMPOSITE; STORAGE;
D O I
10.1007/s10800-014-0716-9
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
CoFe2O4 spheres were synthesized using a microwave-hydrothermal reaction and characterized by X-ray diffraction, electron microscopy, and electrochemical analysis. This simple synthesis method led to a uniform dispersion of nanosized building blocks in the spheres, which exhibit significantly improved cycling performance and rate capability in lithium cells. The excellent electrochemical performances of CoFe2O4 sphere are attributed to an increased lithium wetting property at the electrode-electrolyte interface, facile lithium-ion diffusion, and better alleviation of the structure pulverization during charge-discharge process.
引用
收藏
页码:1069 / 1074
页数:6
相关论文
共 30 条
  • [1] Nanomaterials for rechargeable lithium batteries
    Bruce, Peter G.
    Scrosati, Bruno
    Tarascon, Jean-Marie
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (16) : 2930 - 2946
  • [2] Crumpled Graphene-Molybdenum Oxide Composite Powders: Preparation and Application in Lithium-Ion Batteries
    Choi, Seung Ho
    Kang, Yun Chan
    [J]. CHEMSUSCHEM, 2014, 7 (02) : 523 - 528
  • [3] Ordered porous materials for emerging applications
    Davis, ME
    [J]. NATURE, 2002, 417 (6891) : 813 - 821
  • [4] Direct synthesis of iron oxide nanoparticles on an iron current collector as binder-free anode materials for lithium-ion batteries
    Ding, Yunhai
    Li, Jiaxin
    Zhao, Yi
    Guan, Lunhui
    [J]. MATERIALS LETTERS, 2012, 81 : 105 - 107
  • [5] Synthesis of porous CoFe2O4 octahedral structures and studies on electrochemical Li storage behavior
    Fu, Xinning
    Chen, Dan
    Wang, Min
    Yang, Yushi
    Wu, Qingzhi
    Ma, Jianmin
    Zhao, Xinsheng
    [J]. ELECTROCHIMICA ACTA, 2014, 116 : 164 - 169
  • [6] On the microporous nature of mesoporous molecular sieves
    Göltner, CG
    Smarsly, B
    Berton, B
    Antonietti, M
    [J]. CHEMISTRY OF MATERIALS, 2001, 13 (05) : 1617 - 1624
  • [7] Growth of nanowire superlattice structures for nanoscale photonics and electronics
    Gudiksen, MS
    Lauhon, LJ
    Wang, J
    Smith, DC
    Lieber, CM
    [J]. NATURE, 2002, 415 (6872) : 617 - 620
  • [8] CoFe2O4 and NiFe2O4 synthesized by sol-gel procedures for their use as anode materials for Li ion batteries
    Lavela, P.
    Tirado, J. L.
    [J]. JOURNAL OF POWER SOURCES, 2007, 172 (01) : 379 - 387
  • [9] Self-Assembled Fe3O4 Nanoparticle Clusters as High-Performance Anodes for Lithium Ion Batteries via Geometric Confinement
    Lee, Soo Hong
    Yu, Seung-Ho
    Lee, Ji Eun
    Jin, Aihua
    Lee, Dong Jun
    Lee, Nohyun
    Jo, Hyungyung
    Shin, Kwangsoo
    Ahn, Tae-Young
    Kim, Young-Woon
    Choe, Heeman
    Sung, Yung-Eun
    Hyeon, Taeghwan
    [J]. NANO LETTERS, 2013, 13 (09) : 4249 - 4256
  • [10] Confined Nanospace Pyrolysis for the Fabrication of Coaxial Fe3O4@C Hollow Particles with a Penetrated Mesochannel as a Superior Anode for Li-Ion Batteries
    Lei, Cheng
    Han, Fei
    Sun, Qiang
    Li, Wen-Cui
    Lu, An-Hui
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (01) : 139 - 145