A low-resolution non-invasive NMR characterization of ancient paper

被引:35
作者
Casieri, C
Bubici, S
Viola, I
De Luca, F
机构
[1] Univ Roma La Sapienza, INFM, I-00185 Rome, Italy
[2] Univ Roma La Sapienza, Dipartimento Fis, I-00185 Rome, Italy
[3] Univ Aquila, INFM, I-67100 Laquila, Italy
[4] Univ Aquila, Dipartimento Fis, I-67100 Laquila, Italy
关键词
cultural heritage; single-sided NMR; surface coil; relaxometry; non-destructive analysis; paper; iron-gall ink; NMR on paper;
D O I
10.1016/j.ssnmr.2004.02.001
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The use of a portable NMR device allows a non-invasive investigation of the paper in order to assess the state of conservation of books and documents of historical or artistic interest. The NMR investigation has been found mainly on relaxation measurements whose results seem compatible with different relaxation rates in crystalline and amorphous cellulose domains. By a simplified physical picture based on spin-diffusion it appears possible to detect the alteration of the crystalline/amorphous cellulose balance and therefore to get information on some deterioration processes of paper. The use of a portable NMR device shows great potentiality because of its safe and simple in situ approach to Cultural Heritage documents. In this work, we present a research carried out on a 17th century manuscript. (C) 2004 Elsevier Inc. All rights reserved.
引用
收藏
页码:65 / 73
页数:9
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