Highly efficient iron phthalocyanine catalyzed oxidative synthesis of imines from alcohols and amines

被引：20

作者：

Bala, Manju ^{[1
]}

Verma, Praveen Kumar ^{[1
]}

Kumar, Neeraj ^{[1
]}

Sharma, Upendra ^{[1
]}

Singh, Bikram ^{[1
]}

机构：

[1] Inst Himalayan Bioresource Technol, CSIR, Nat Plant Prod Div, Palampur 176061, Himachal Prades, India

来源：

CANADIAN JOURNAL OF CHEMISTRY | 2013年 / 91卷 / 08期

关键词：

iron phthalocyanine; imine synthesis; oxidative coupling; alcohols; amines; ASYMMETRIC TRANSFER HYDROGENATION; ONE-POT SYNTHESIS; REDUCTION; COMPLEXES; RUTHENIUM; SECONDARY;

D O I：

10.1139/cjc-2012-0399

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient iron phthalocyanine catalyzed method was developed for direct oxidative coupling of alcohols with amines to afford corresponding imines. The present protocol is applicable to various substituted aromatic and aliphatic alcohols and amines. The reaction is believed to proceed via activation of alcohols by iron phthalocyanines through Lewis acid-base interaction to form aldehydes, which by nucleophilic attack of amines are converted into the corresponding imines.

引用

页码：732 / 737

页数：6

共 50 条

[11] Activated Carbon Supported Ruthenium Nanoparticles Catalyzed Synthesis of Imines from Aerobic Oxidation of Alcohols with Amines
Zhang, Yuecheng
Lu, Fei
Zhang, Hong-Yu
Zhao, Jiquan
CATALYSIS LETTERS, 2017, 147 (01) : 20 - 28
[12] Vanadium- and Chromium-Catalyzed Dehydrogenative Synthesis of Imines from Alcohols and Amines
Miao, Yulong
Samuelsen, Simone, V
Madsen, Robert
ORGANOMETALLICS, 2021, 40 (09) : 1328 - 1335
[13] Efficient Synthesis of Imines by Oxidative Coupling Catalyzed by Ce-Mn Oxide Microspheres
Chutimasakul, Threeraphat
Tirdtrakool, Warinda
Nakhonpanom, Pakamon Na
Kreethatorn, Hemmarat
Jaruwatee, Pattamaporn
Bunchuay, Thanthapatra
Tantirungrotechai, Jonggol
CHEMISTRYSELECT, 2022, 7 (33):
[14] Iron-Catalyzed Synthesis of Amines and Thioethers Directly from Allylic Alcohols
Wang, Dan-Yang
Peng, Xiao-Min
Wang, Guang-Zhu
Zhang, Ya-Juan
Guo, Tao
Zhang, Pan-Ke
ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2018, 7 (05) : 875 - 878
[15] Silver-catalyzed efficient synthesis of enaminones from propargyl alcohols and amines
Li, Mengshun
Fang, Dongmei
Geng, Feng
Dai, Xianping
TETRAHEDRON LETTERS, 2017, 58 (51) : 4747 - 4749
[16] Direct and mild palladium-catalyzed aerobic oxidative synthesis of imines from alcohols and amines under ambient conditions
Jiang, Lan
Jin, Luolu
Tian, Haiwen
Yuan, Xueqin
Yu, Xiaochun
Xu, Qing
CHEMICAL COMMUNICATIONS, 2011, 47 (38) : 10833 - 10835
[17] Activated Carbon Supported Ruthenium Nanoparticles Catalyzed Synthesis of Imines from Aerobic Oxidation of Alcohols with Amines
Yuecheng Zhang
Fei Lu
Hong-Yu Zhang
Jiquan Zhao
Catalysis Letters, 2017, 147 : 20 - 28
[18] Cobalt-Catalyzed Acceptorless Alcohol Dehydrogenation: Synthesis of Imines from Alcohols and Amines
Zhang, Guoqi
Hanson, Susan K.
ORGANIC LETTERS, 2013, 15 (03) : 650 - 653
[19] Aerobic oxidative coupling of alcohols and amines to imines over iron catalysts supported on mesoporous carbon
Geng, Longlong
Song, Jinling
Zheng, Bin
Wu, Shujie
Zhang, Wenxiang
Jia, Mingjun
Liu, Gang
CHINESE JOURNAL OF CATALYSIS, 2016, 37 (09) : 1451 - 1460
[20] Base-Mediated Synthesis of Imines and Amines from N-Phenylureas and Alcohols
Yadav, Dilip Kumar T.
Bhanage, Bhalchandra M.
SYNLETT, 2014, 25 (11) : 1611 - 1615

← 1 2 3 4 5 →