Highly efficient iron phthalocyanine catalyzed oxidative synthesis of imines from alcohols and amines

被引：21

作者：

Bala, Manju ^{[1
]}

Verma, Praveen Kumar ^{[1
]}

Kumar, Neeraj ^{[1
]}

Sharma, Upendra ^{[1
]}

Singh, Bikram ^{[1
]}

机构：

[1] Inst Himalayan Bioresource Technol, CSIR, Nat Plant Prod Div, Palampur 176061, Himachal Prades, India

来源：

CANADIAN JOURNAL OF CHEMISTRY | 2013年 / 91卷 / 08期

关键词：

iron phthalocyanine; imine synthesis; oxidative coupling; alcohols; amines; ASYMMETRIC TRANSFER HYDROGENATION; ONE-POT SYNTHESIS; REDUCTION; COMPLEXES; RUTHENIUM; SECONDARY;

D O I：

10.1139/cjc-2012-0399

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient iron phthalocyanine catalyzed method was developed for direct oxidative coupling of alcohols with amines to afford corresponding imines. The present protocol is applicable to various substituted aromatic and aliphatic alcohols and amines. The reaction is believed to proceed via activation of alcohols by iron phthalocyanines through Lewis acid-base interaction to form aldehydes, which by nucleophilic attack of amines are converted into the corresponding imines.

引用

页码：732 / 737

页数：6