Palladium-coated thiourea core-shell nanocomposite as a new, efficient, and magnetic responsive nanocatalyst for the Suzuki-Miyaura coupling reactions

被引:7
作者
Eivazzadeh-Keihan, Reza [1 ]
Bahrami, Negar [1 ]
Radinekiyan, Fateme [1 ]
Maleki, Ali [1 ]
Mahdavi, Mohammad [2 ]
机构
[1] Iran Univ Sci & Technol, Dept Chem, Catalysts & Organ Synth Res Lab, Tehran 1684613114, Iran
[2] Univ Tehran Med Sci, Endocrinol & Metab Clin Sci Inst, Endocrinol & Metab Res Ctr, Tehran, Iran
关键词
Suzuki-Miyaura coupling reaction; Functionalized Fe3O4 magnetic nanoparticles; thiourea; palladium; magnetic responsive catalyst; HEAVY-METAL; NANOPARTICLES; DESIGN; RESIN; DERIVATIVES; ADSORPTION; CATALYST; REMOVAL; GEL;
D O I
10.1088/2053-1591/abe320
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this research, according to the important aspects of palladium components in conducting Suzuki-Miyaura coupling reactions and formation of biphenyl compounds, magnetic responsive palladium/thiourea nanocomposite as a new magnetic nanocatalyst was designed, synthesized, and characterized using FT-IR, EDX, FE-SEM, and VSM analyses. The catalytic performance of this new nanocomposite with magnetic susceptibility was evaluated in the Suzuki-Miyaura coupling reaction. Based on the functionalized surface of Fe3O4 magnetic cores with SiO2, CPTMS, thiourea shells, and especially Palladium ions shell, the formation of biphenyl derivatives in a green and eco-friendly reaction condition was highlighted.
引用
收藏
页数:14
相关论文
共 68 条
[51]   Antioxidant properties of some thiourea derivatives [J].
Sudzhaev, A. R. ;
Rzaeva, I. A. ;
Nadzhafova, R. A. ;
Safarov, Yu. S. ;
Allakhverdiev, M. A. .
RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2011, 84 (08) :1394-1397
[52]  
Sun AW., 2003, CHINESE J SOIL SCI, V4
[53]   Efficient synthesis of PtPd/Fe3O4 nanoparticles and its magnetic recoverability and stable recyclability for the Heck and Suzuki reactions [J].
Sun, Yuanxu ;
Zhu, Xiaoqing ;
Guo, Dandan ;
Chen, Xiao ;
Dai, Jingtao .
MATERIALS RESEARCH EXPRESS, 2017, 4 (07)
[55]  
Trivedi M.K., 2015, MODERN CHEM APPL, V3, P1, DOI DOI 10.4172/2329-6798.1000159
[56]   Silver(I) and palladium(II) complexes of new pentamethylene-functionalized bis-imidazolium dication ligands and its application in Heck and Suzuki-Miyaura coupling reaction [J].
Trivedi, Manoj ;
Bhaskaran ;
Singh, Gurmeet ;
Kumar, Abhinav ;
Rath, Nigam P. .
INORGANICA CHIMICA ACTA, 2016, 449 :1-8
[57]   Design of epoxy-functionalized Fe3O4@MCM-41 core-shell nanoparticles for enzyme immobilization [J].
Ulu, Ahmet ;
Ozcan, Imren ;
Koytepe, Suleyman ;
Ates, Burhan .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2018, 115 :1122-1130
[58]   Palladium anchored to SBA-15 functionalized with melamine-pyridine groups as a novel and efficient heterogeneous nanocatalyst for Suzuki-Miyaura coupling reactions [J].
Veisi, Hojat ;
Hamelian, Mona ;
Hemmati, Saba .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2014, 395 :25-33
[59]   Synthesis and characterization of 3-[(thiourea)-propyl]-functionalized silica gel and its application in adsorption and catalysis [J].
Vieira, Eduardo Guimaraes ;
Soares, Isaac Vaz ;
da Silva, Nileia Cristina ;
Perujo, Sergio Daniel ;
do Carmo, Devaney Ribeiro ;
Dias Filho, Newton Luiz .
NEW JOURNAL OF CHEMISTRY, 2013, 37 (07) :1933-1943
[60]   Functionalization of Fe3O4 NPs by Silanization: Use of Amine (APTES) and Thiol (MPTMS) Silanes and Their Physical Characterization [J].
Villa, Silvia ;
Riani, Paola ;
Locardi, Federico ;
Canepa, Fabio .
MATERIALS, 2016, 9 (10)