Palladium-coated thiourea core-shell nanocomposite as a new, efficient, and magnetic responsive nanocatalyst for the Suzuki-Miyaura coupling reactions

被引:7
作者
Eivazzadeh-Keihan, Reza [1 ]
Bahrami, Negar [1 ]
Radinekiyan, Fateme [1 ]
Maleki, Ali [1 ]
Mahdavi, Mohammad [2 ]
机构
[1] Iran Univ Sci & Technol, Dept Chem, Catalysts & Organ Synth Res Lab, Tehran 1684613114, Iran
[2] Univ Tehran Med Sci, Endocrinol & Metab Clin Sci Inst, Endocrinol & Metab Res Ctr, Tehran, Iran
关键词
Suzuki-Miyaura coupling reaction; Functionalized Fe3O4 magnetic nanoparticles; thiourea; palladium; magnetic responsive catalyst; HEAVY-METAL; NANOPARTICLES; DESIGN; RESIN; DERIVATIVES; ADSORPTION; CATALYST; REMOVAL; GEL;
D O I
10.1088/2053-1591/abe320
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this research, according to the important aspects of palladium components in conducting Suzuki-Miyaura coupling reactions and formation of biphenyl compounds, magnetic responsive palladium/thiourea nanocomposite as a new magnetic nanocatalyst was designed, synthesized, and characterized using FT-IR, EDX, FE-SEM, and VSM analyses. The catalytic performance of this new nanocomposite with magnetic susceptibility was evaluated in the Suzuki-Miyaura coupling reaction. Based on the functionalized surface of Fe3O4 magnetic cores with SiO2, CPTMS, thiourea shells, and especially Palladium ions shell, the formation of biphenyl derivatives in a green and eco-friendly reaction condition was highlighted.
引用
收藏
页数:14
相关论文
共 68 条
[1]   New bifunctional carbohydrate-like thiourea derivatives - design and first application in organocatalysis [J].
Adam, Lutz ;
Schefzig, Luise ;
Pecchioli, Tommaso ;
Zimmer, Reinhold ;
Reissig, Hans-Ulrich .
SYNTHETIC COMMUNICATIONS, 2018, 48 (15) :1945-1956
[2]   N1,N1-Dimethylpropane-1,2-diaminium bis(6-carboxypyridine-2-carboxylate) monohydrate [J].
Aghabozorg, Hossein ;
Foroughian, Mahsa ;
Foroumadi, Alireza ;
Bruno, Giuseppe ;
Rudbari, Hadi Amiri .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 :O932-U1039
[3]   Design and application of thiourea modified D301 resin for the effective removal of toxic heavy metal ions [J].
An, Fu-Qiang ;
Wang, Yong ;
Xue, Xiao-Yan ;
Hu, Tuo-Ping ;
Gao, Jian-Feng ;
Gao, Bao-Jiao .
CHEMICAL ENGINEERING RESEARCH & DESIGN, 2018, 130 :78-86
[4]   Chiral Bifunctional Thioureas and Squaramides and Their Copolymers as Recoverable Organocatalysts. Stereoselective Synthesis of 2-Substituted 4-Amino-3-nitrobenzopyrans and 3-Functionalized 3,4-Diamino-4H-Chromenes [J].
Andres, Jose M. ;
Maestro, Alicia ;
Valle, Maria ;
Pedrosa, Rafael .
JOURNAL OF ORGANIC CHEMISTRY, 2018, 83 (10) :5546-5557
[5]  
[Anonymous], 1994, Sulfur Rep, DOI DOI 10.1080/01961779408048967
[6]   Evolution of the doping regimes in the Al-doped SnO2 nanoparticles prepared by a polymer precursor method [J].
Aragon, F. H. ;
Coaquira, J. A. H. ;
Villegas-Lelovsky, L. ;
da Silva, S. W. ;
Cesar, D. F. ;
Nagamine, L. C. C. M. ;
Cohen, R. ;
Menendez-Proupin, E. ;
Morais, P. C. .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2015, 27 (09)
[7]   Preparation of a novel magnetic bionanocomposite based on factionalized chitosan by creatine and its application in the synthesis of polyhydroquinoline, 1,4-dyhdropyridine and 1,8-dioxo-decahydroacridine derivatives [J].
Asgharnasl, Somayeh ;
Eivazzadeh-Keihan, Reza ;
Radinekiyan, Fateme ;
Maleki, Ali .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2020, 144 :29-46
[8]   Palladium Complex Immobilized on Graphene Oxide as an Efficient and Recyclable Catalyst for Suzuki Coupling Reaction [J].
Bai, Chan ;
Zhao, Qingshan ;
Li, Yang ;
Zhang, Guoliang ;
Zhang, Fengbao ;
Fan, Xiaobin .
CATALYSIS LETTERS, 2014, 144 (09) :1617-1623
[9]   Casein-Coated Iron Oxide Nanoparticles for in vitro Hyperthermia for Cancer Therapy [J].
Bani, Milad Salimi ;
Hatamie, Shadie ;
Haghpanahi, Mohammad ;
Bahreinizad, Hossein ;
Alavijeh, Mohammad Hossein Shahsavari ;
Eivazzadeh-Keihan, Reza ;
Wei, Zhung Hang .
SPIN, 2019, 9 (02)
[10]   Pd(N,N-dimethyl β-alaninate)2 as a high-turnover-number, phosphine-free catalyst for the Suzuki reaction [J].
Cui, Xin ;
Qin, Tian ;
Wang, Jia-Rui ;
Liu, Lei ;
Guo, Qing-Xiang .
SYNTHESIS-STUTTGART, 2007, (03) :393-399