A sustainable protocol for the facile synthesis of zinc-glutamate MOF: an efficient catalyst for room temperature CO2 fixation reactions under wet conditions

被引：149

作者：

Kathalikkattil, Amal Cherian ^{[1
]}

Roshan, Roshith ^{[1
]}

Tharun, Jose ^{[1
]}

Babu, Robin ^{[1
]}

Jeong, Gyeong-Seon ^{[1
]}

Kim, Dong-Woo ^{[2
]}

Cho, Sung June ^{[3
]}

Park, Dae-Won ^{[1
]}

机构：

[1] Pusan Natl Univ, Sch Chem & Biomol Engn, Busan 609735, South Korea

[2] Korea Res Inst Chem Technol, Res Ctr Green Fine Chem, Div Ulsan, Ulsan 681802, South Korea

[3] Chonnam Natl Univ, Dept Chem Engn, Gwangju, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 02期

基金：

新加坡国家研究基金会;

关键词：

METAL-ORGANIC FRAMEWORK; STYRENE CARBONATE SYNTHESIS; ONE-POT-SYNTHESIS; CYCLIC CARBONATES; HETEROGENEOUS CATALYST; CRYSTAL-STRUCTURE; IONIC LIQUIDS; N-DONOR; DIOXIDE; CAPTURE;

D O I：

10.1039/c5cc07781h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A water stable zinc-MOF (ZnGlu) catalyst was facilely prepared from the proteinogenic amino acid, L-glutamic acid at room temperature in aqueous medium. CO2 fixations were promoted by the ZnGlu catalyst's inherently coordinated water and externally added water in yielding cyclic carbonate and cyclic urethane at room temperature. This eliminates the need for catalyst activation, making ZnGlu a ready-to-use catalyst. The enhanced CO2 cycloaddition with added water hints at the application of ZnGlu in wet flue gas conversions. This is the first reported attempt for the use of an MOF in the cycloaddition of aziridine and CO2.

引用

页码：280 / 283

页数：4

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