Crystal structure and IR spectrum of diaqua(o-phenanthroline) bis(saccharinato)lead(II)

被引：0
作者：
Baran, EJ
Wagner, CC
Rossi, M
Caruso, F
机构：
[1] Natl Univ La Plata, Fac Ciencias Exactas, CEQUINOR, CONICET, RA-1900 La Plata, Argentina
[2] Vassar Coll, Dept Chem, Poughkeepsie, NY 12601 USA
[3] CNR, Ist Strutturist Chim G Giacomello, I-00016 Rome, Italy
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2000年 / 626卷 / 03期
关键词：
crystal structure; lead complexes; saccharinates; IR spectroscopy;
D O I：
10.1002/(SICI)1521-3749(200003)626:3<701::AID-ZAAC701>3.0.CO;2-O
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structure of [Pb(sac)(2)ophen(H2O)(2)] (sac = saccharinate anion; ophen = 1,10-phenanthroline) has been solved by single X-ray diffractometry. It crystallizes in the monoclinic space group C2/c with Z = 4. The Pb-II atom presents the coordination number eight with unusual coordination of the ligand atoms between square-antiprism and dodecahedron. The saccharinate anion acts as a bidentate ligand. The i.r. spectrum of the complex has been analyzed in detail and assigned on the basis of the structural peculiarities.
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页码：701 / 705
页数：5
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