RICE HUSK ASH: A NEW, CHEAP, EFFICIENT, AND REUSABLE REAGENT FOR THE PROTECTION OF ALCOHOLS, PHENOLS, AMINES, AND THIOLS

被引：7

作者：

Shirini, F. ^{[1
]}

Akbari-Dadamahaleh, Somayeh ^{[1
]}

Mohammad-Khah, Ali ^{[1
]}

机构：

[1] Univ Guilan, Dept Chem, Coll Sci, Rasht 41335, Iran

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2014年 / 189卷 / 05期

关键词：

Rice husk ash (RiHA); heterogenous reagent; trimethylsilylation; acetylation; protection; mild reaction conditions; RECYCLABLE HETEROGENEOUS CATALYST; SOLVENT-FREE; HIGHLY EFFICIENT; HYDROXYL-GROUPS; SILICA-GEL; HEXAMETHYLDISILAZANE HMDS; TRIMETHYLSILYL PROTECTION; ACETIC-ANHYDRIDE; AQUEOUS-SOLUTION; ZSM-5; ZEOLITE;

D O I：

10.1080/10426507.2013.844142

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A mild, efficient, and eco-friendly protocol for the protection of alcohols and phenols as trimethylsilyl ethers has been developed using rice husk ash as a reagent. This reagent is also able to catalyze the acetylation of alcohols, phenols, thiols, and amines with acetic anhydride. All reactions were performed under mild conditions in good to high yields.

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页码：577 / 586

页数：10

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