Bis(2-pyridylmethyl)ammonium perchlorate

被引：3

作者：

Butcher, RJ ^{[1
]}

Gultneh, Y ^{[1
]}

Khan, AR ^{[1
]}

机构：

[1] Howard Univ, Dept Chem, Washington, DC 20059 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2002年 / 58卷

关键词：

D O I：

10.1107/S1600536802012527

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, C12H14N3+.ClO4-, crystallizes from a solution of bis(2-pyridylmethyl)amine and HClO4 in water/DMF (3:1, v/v) with the secondary amine N atom protonated. The two pyridine arms of the ligand are held in a closed conformation through a strong bifurcated hydrogen bond from one of the ammonium H atoms. The ClO4- anion is also hydrogen bonded to the same H atom of the ammonium N atom, with an N...O distance of 2.899 (4) Angstrom. The other ammonium H atom is hydrogen bonded to an O atom of a symmetry-related perchlorate anion.

引用

页码：o858 / o859

页数：2

共 5 条

[1] Syntheses and structures of and catalysis of hydrolysis by Zn(II) complexes of chelating pyridyl donor ligands [J].