Copper-catalyzed direct oxidation and N-arylation of benzylamines with diaryliodonium salts

被引：5
|
作者：
Liu Xin
Mao Dan
Wu ShengYing
Yu JianJun
Hong Gang
Zhao Qiao
Wang LiMin [1 ]
机构：
[1] E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China
来源：
SCIENCE CHINA-CHEMISTRY | 2014年 / 57卷 / 08期
关键词：
copper(II) triflate; diaryliodonium salts; N-arylated amides; oxidation; BOND-FORMING REACTIONS; ARYL HALIDES; C-ARYLATION; CASCADE ANNULATION; COUPLING REACTIONS; POLYVALENT IODINE; GOLDBERG REACTION; MOLECULAR-OXYGEN; ROOM-TEMPERATURE; IODONIUM SALTS;
D O I：
10.1007/s11426-014-5140-9
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient approach for the synthesis of N-arylated amides was developed via copper(II) triflate-catalyzed direct oxidation of (aryl)methylamines to primary arylamides by air and subsequent N-arylation by diaryliodonium salts. Various substituted benzylamines could be applied in the reaction, providing a series of N-arylated amides in moderate to good yields. This method showed convenient, practical, and environment friendly advantages.
引用
收藏
页码：1132 / 1136
页数：5
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