Thiophenic silicon phthalocyanines: synthesis, characterization, and photophysical properties

被引：2

作者：

Chen, Kuizhi ^{[1
]}

Li, Xia ^{[1
]}

Huang, Bingcheng ^{[1
]}

Ye, Qiuhao ^{[1
]}

Xiao, Wenling ^{[1
]}

Guan, Xinqiao ^{[1
]}

Chen, Limin ^{[2
]}

Peng, Yiru ^{[1
]}

机构：

[1] Fujian Normal Univ, Coll Chem & Mat, Fujian Prov Key Lab Polymer Mat, Fujian Prov Key Lab Adv Mat Oriented Chem Engn, Fuzhou 350007, Peoples R China

[2] Fujian Med Univ, Affiliated Hosp, Fuzhou 350004, Peoples R China

来源：

NEW JOURNAL OF CHEMISTRY | 2021年 / 45卷 / 01期

关键词：

PHOTODYNAMIC THERAPY;

D O I：

10.1039/d0nj04355a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three new thienyl/benzothienyl/dibenzothienyl groups axially substituted silicon(iv) phthalocyanines were synthesized. The structures of these thiophenic silicon(iv) phthalocyanines were characterized. The influence of different thiophenic substituents on the photophysical/photochemical properties of phthalocyanines was investigated by fluorescence and UV/Vis absorption spectroscopies. Among them, benzothienyl group substituted silicon(iv) phthalocyanine possessed the highest fluorescence intensity, lifetime, and singlet oxygen quantum yield. Benzothienyl group substituted silicon(iv) phthalocyanine could be transported into MCF-7 breast cancer cells and was not evenly distributed in the cytoplasm, and mediated photodynamic therapy to kill cancer cells.

引用

页码：457 / 462

页数：6

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