Cyclic carbonate formation from carbon dioxide and oxiranes in tetrabutylammonium halides as solvents and catalysts

被引：521

作者：

Caló, V ^{[1
]}

Nacci, A ^{[1
]}

Monopoli, A ^{[1
]}

Fanizzi, A ^{[1
]}

机构：

[1] Ist Chim Composti Organometall, Dept Chem, Sezione Bari, I-70126 Bari, Italy

来源：

ORGANIC LETTERS | 2002年 / 4卷 / 15期

关键词：

D O I：

10.1021/ol026189w

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Epoxides dissolved in molten tetralkylammonium salts bearing halides as counterions are converted into cyclic carbonates under atmospheric pressure of carbon dioxide. The reaction rate depends on the nucleophilicity of the halide ion as well as the structure of the cation.

引用

页码：2561 / 2563

页数：3

共 50 条

[11] Effect of the structure of alkylammonium halides on the outcome of carbon dioxide cycloaddition to oxiranes [J].

Gabov, I. S. ;

Ezhikova, M. A. ;

Kodess, M. I. ;

Pestov, A. V. .

RUSSIAN CHEMICAL BULLETIN, 2023, 72 (12) :2809-2814

[12] COPOLYMERIZATION OF CARBON-DIOXIDE AND SOME OXIRANES BY ORGANOALUMINUM CATALYSTS [J].

KOINUMA, H ;

HIRAI, H .

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS, 1977, 178 (05) :1283-1294

[13] Effective synthesis of cyclic carbonates from carbon dioxide and epoxides by phosphonium iodides as catalysts in alcoholic solvents [J].

Aoyagi, Naoto ;

Furusho, Yoshio ;

Endo, Takeshi .

TETRAHEDRON LETTERS, 2013, 54 (51) :7031-7034

[14] Coordination complexes as catalysts for the coupling reactions of oxiranes and carbon dioxide [J].

Bhat, Gulzar A. ;

Darensbourg, Donald J. .

COORDINATION CHEMISTRY REVIEWS, 2023, 492

[15] Significant rate acceleration in carbonate synthesis from carbon dioxide and oxiranes using dimethyl carbonate as a recyclable medium [J].

Kumar, Subodh ;

Jain, Suman L. ;

Sain, Bir .

TETRAHEDRON LETTERS, 2011, 52 (51) :6957-6959

[16] Catalytic performance and properties of ceria based catalysts for cyclic carbonate synthesis from glycol and carbon dioxide [J].

Tomishige, K ;

Yasuda, H ;

Yoshida, Y ;

Nurunnabi, M ;

Li, BT ;

Kunimori, K .

GREEN CHEMISTRY, 2004, 6 (04) :206-214

[17] Sodium and potassium halides as catalysts for the addition of carbon dioxide to epoxides: the effect of co-solvents [J].

S. E. Lyubimov ;

A. A. Zvinchuk ;

B. Chowdhury .

Russian Chemical Bulletin, 2021, 70 :732-734

[18] Sodium and potassium halides as catalysts for the addition of carbon dioxide to epoxides: the effect of co-solvents [J].

Lyubimov, S. E. ;

Zvinchuk, A. A. ;

Chowdhury, B. .

RUSSIAN CHEMICAL BULLETIN, 2021, 70 (04) :732-734

[19] METAL-CATALYZED SYNTHESIS OF CYCLIC CARBONATES FROM CARBON-DIOXIDE AND OXIRANES [J].

RATZENHOFER, M ;

KISCH, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1980, 19 (04) :317-318

[20] Synthesis of Cyclic Chloropropylene Carbonate from Carbon Dioxide with Epichlorohydrin [J].

Li, Hongchun ;

Nni, Yongsheng .

ASIAN JOURNAL OF CHEMISTRY, 2011, 23 (08) :3344-3346

← 1 2 3 4 5 →