Cyclic carbonate formation from carbon dioxide and oxiranes in tetrabutylammonium halides as solvents and catalysts

被引：512

作者：

Caló, V ^{[1
]}

Nacci, A ^{[1
]}

Monopoli, A ^{[1
]}

Fanizzi, A ^{[1
]}

机构：

[1] Ist Chim Composti Organometall, Dept Chem, Sezione Bari, I-70126 Bari, Italy

来源：

ORGANIC LETTERS | 2002年 / 4卷 / 15期

关键词：

D O I：

10.1021/ol026189w

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Epoxides dissolved in molten tetralkylammonium salts bearing halides as counterions are converted into cyclic carbonates under atmospheric pressure of carbon dioxide. The reaction rate depends on the nucleophilicity of the halide ion as well as the structure of the cation.

引用

页码：2561 / 2563

页数：3

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