A Pd(II)-Catalyzed Ring-Expansion Reaction of Cyclic 2-Azidoalcohol Derivatives: Synthesis of Azaheterocycles

被引：111

作者：

Chiba, Shunsuke ^{[1
]}

Xu, Yan-Jun ^{[1
]}

Wang, Yi-Feng ^{[1
]}

机构：

[1] Nanyang Technol Univ, Div Chem & Biol Chem, Sch Phys & Math Sci, Singapore 637371, Singapore

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 36期

关键词：

PALLADIUM-CATALYZED ARYLATION; CARBON-CARBON BOND; C-H BOND; TERT-CYCLOBUTANOLS; CLEAVAGE; NITRILES; AZIDES; CYCLIZATION; AMINATION; CHEMISTRY;

D O I：

10.1021/ja9049564

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A Pd(II)-catalyzed ring expansion-reaction of cyclic 2-azidoalcohol derivatives was found to proceed via an unprecedented C-C bond cleavage-C-N bond formation sequence, providing substituted azaheterocycles.

引用

页码：12886 / +

页数：3

共 31 条

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