FLP catalysis: main group hydrogenations of organic unsaturated substrates

被引：294

作者：

Lam, Jolie ^{[1
]}

Szkop, Kevin M. ^{[1
]}

Mosaferi, Eliar ^{[1
]}

Stephan, Douglas W. ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, 80 St George St, Toronto, ON M5S3H6, Canada

来源：

CHEMICAL SOCIETY REVIEWS | 2019年 / 48卷 / 13期

基金：

加拿大自然科学与工程研究理事会;

关键词：

FRUSTRATED LEWIS PAIRS; METAL-FREE HYDROGENATION; HIGHLY ENANTIOSELECTIVE HYDROGENATION; ASYMMETRIC HYDROGENATION; STEREOSELECTIVE HYDROGENATION; (FLP)-CATALYZED HYDROGENATION; SELECTIVE HYDROGENATION; FACILE PROTOCOL; OXIME ETHERS; BORANE;

D O I：

10.1039/c8cs00277k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This article is focused on recent developments in main group mediated hydrogenation chemistry and catalysis using "frustrated Lewis pairs" (FLPs). The broading range of substrates and catalyst systems is reviewed and the advances in catalytic reductions and the development of stereoselective, asymmetric reductions made since 2012 is considered.

引用

页码：3592 / 3612

页数：21

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