Synthesis and crystal structure of a novel supra-molecular compound [Co(tsc)2][NPA]2 • 4H2O (tsc = thiosemicarbazide, H2NPA=3-nitro-phthalic acid)

被引：3

作者：

Yang, Rui ^{[1
]}

Shen, Xiao-Qing ^{[1
]}

Mao, Hong-Yan ^{[1
]}

Zhang, Hong-Yun ^{[1
]}

Wu, Qing-An ^{[1
]}

Wang, Hui ^{[1
]}

Hou, Hong-Wei ^{[1
]}

Zhu, Yu ^{[1
]}

机构：

[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2006年 / 36卷 / 08期

基金：

美国国家科学基金会;

关键词：

hydrogen bond; cobalt; carboxylate; crystal structure; thiosemicarbazide;

D O I：

10.1080/15533170600910538

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The supramolecular compound [Co(tsc)(2)][NPA](2) center dot 4H(2)O has been synthesized, with its crystal structure characterized by IR spectrum and X-ray crystallography diffraction. It belongs to triclinic crystal with p-1 space group. Unit cell dimensions are a = 6.6585(13) angstrom, b = 6.6585(13) angstrom, c = 13.871(3) angstrom; alpha = 86.64(3)degrees, beta = 89.78(3)degrees, gamma = 75.42(3)degrees, V = 717.9(2) angstrom(3). Characterization reveals that 3-nitro-hphthalate anions as hydrogen bond acceptor bonds to two different cations in parallel and vertical directions, respectively. All of the potential hydrogen bond donors and acceptors are involved in hydrogen bonds, leading to a 2D supramolecular layer structure.

引用

页码：617 / 620

页数：4

共 16 条

[1] Crystal engineering: Strategies and architectures [J].

Aakeroy, CB .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1997, 53 :569-586

[2] Hydrogen bond directed crystal engineering of nickel complexes: the effect of ligand methyl substituents on supramolecular structure [J].

Allen, MT ;

Burrows, AD ;

Mahon, MF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (02) :215-221

[3] Zinc thiosemicarbazide dicarboxylates: the influence of the anion shape on supramolecular structure [J].

Babb, JEV ;

Burrows, AD ;

Harrington, RW ;

Mahon, MF .

POLYHEDRON, 2003, 22 (05) :673-686

[4] The structural influence of ligand coordination and hydrogen bonding capabilities in the crystal engineering of metal thiosemicarbazide compounds with malonate [J].

Burrows, AD ;

Harrington, RW ;

Mahon, MF ;

Teat, SJ .

CRYSTENGCOMM, 2005, 7 :388-397

[5] Manipulation of molecular and supramolecular structure in nickel(II) complexes through the orientation of dicarboxylate hydrogen bonding faces [J].

Burrows, AD ;

Harrington, RW ;

Mahon, MF ;

Teat, SJ .

CRYSTAL GROWTH & DESIGN, 2004, 4 (04) :813-822

[6] The influence of the chelate effect on supramolecular structure formation: synthesis and crystal structures of zinc thiourea and and thiosemicarbazide complexes with terephthalate [J].

Burrows, AD ;

Menzer, S ;

Mingos, DMP ;

White, AJP ;

Williams, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (22) :4237-4240

[7] Crystal engineering of metal complexes based on charge-augmented double hydrogen-bond interactions between thiosemicarbazides and carboxylates [J].

Burrows, AD ;

Mingos, DMP ;

White, AJP ;

Williams, DJ .

CHEMICAL COMMUNICATIONS, 1996, (01) :97-99

[8]

BURROWS AD, 2000, CRYSTENGCOMM, V12, P77

[9] ENCODING AND DECODING HYDROGEN-BOND PATTERNS OF ORGANIC-COMPOUNDS [J].

ETTER, MC .

ACCOUNTS OF CHEMICAL RESEARCH, 1990, 23 (04) :120-126

[10]

HUANG YG, 2005, CHIN J STRUCT CHEM, V24

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