The first triisopropylstibane ruthenium(II) and ruthenium(O) complexes including the X-ray crystal structure of [Ru(eta(3)-C3H5)(2)(SbiPr(3))(2)]

被引：12

作者：

Werner, H

Grunwald, C

Laubender, M

Gevert, O

机构：

[1] Institut Für Anorganische Chemie, Universität Würzburg, D-97074 Würzburg, Am Hubiand

来源：

CHEMISCHE BERICHTE | 1996年 / 129卷 / 10期

关键词：

ruthenium complexes; stibane complexes; dihydrogen complexes; butadiene complex; pi-allyl complex;

D O I：

10.1002/cber.19961291008

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydridoruthenium (II) complexes [RuHCl(H-2)(SbiPr(3))(3)] (2) and [RuH2(H-2)(SibiPr(3))(3)] (3), containing dihydrogen as ligand, were prepared from [RuCl2(C8H12)](n) (1) as the starting material. Compound 3 reacts with CO by displacement of H-2 to yield [RuH2(CO)(SbiPr(3))(3)] (4) and with C2H4 to give both [RuH2(C2H4)(2)(SbiPr(3))(2)] (5) and [RuH2(C2H4)(SbiPr(3))(3)] (6), the latter as the more stable and isolable product. Treatment of 3 with propene leads to the formation of [Ru(eta(3)-C3H5)(2)(SbiPr(3))(2)] (7) while the reaction of 3 with butadiene affords the pentacoordinated ruthenium(0) compound [Ru(eta(4)-C4H6)(2)(SbiPr(3))] (8). The molecular structure of the bis-(allyl) complex 7 was determined by X-ray crystallography.

引用

页码：1191 / 1194

页数：4

共 33 条

[1]

Albers M. O., 1989, INORG SYNTH, V26

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