Investigating the effect of gas absorption on the electromechanical and electrochemical behavior of graphene/ZnO structure, suitable for highly selective and sensitive gas sensors

被引:26
作者
Khadem, S. M. Jebreiil [1 ]
Abdi, Y. [1 ]
Darbari, S. [2 ]
Ostovari, F. [1 ,2 ]
机构
[1] Univ Tehran, Dept Phys, Nanophys Res Lab, Tehran, Iran
[2] Univ Tarbiat Modares, ECE Dept, Tehran, Iran
基金
美国国家科学基金会;
关键词
Graphene; ZnO; Gas sensor; Electromechanical; Electrochemical; LAYER GRAPHENE; GRAPHITE OXIDE; ZNO NANORODS; SINGLE-LAYER; CARBON; ETHANOL; REDUCTION; NANOWIRE; ARRAYS; PHASE;
D O I
10.1016/j.cap.2014.07.020
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Graphene/ZnO hybrid was used, for the first time, to fabricate a highly selective and sensitive graphene based gas sensor by a combination of electromechanical and electrochemical characteristics of the graphene. ZnO nanowires in our fabricated sensor have two important roles: as the reductant of graphene oxide to obtain graphene and as an efficient electromechanical actuator due to their piezoelectric properties. To investigate the operation of the fabricated sensor as a gas sensor, a selected set of chemical vapors were introduced to the structure. It was found that chemical vapors change the resonance frequency of the graphene/ZnO structure, as well as the electrical resistivity of the sensor. The observed variation of the mechanical and electrical characteristics of the graphene/ZnO in response to gas exposure entitles the graphene/ZnO based sensor as a highly selective/sensitive device for gas sensing applications with distinctive signatures for different gas species. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:1498 / 1503
页数:6
相关论文
共 29 条
[1]   Photocatalytic reduction of graphene oxides hybridized by ZnO nanoparticles in ethanol [J].
Akhavan, O. .
CARBON, 2011, 49 (01) :11-18
[2]   Dual-mode mechanical resonance of individual ZnO nanobelts [J].
Bai, XD ;
Gao, PX ;
Wang, ZL ;
Wang, EG .
APPLIED PHYSICS LETTERS, 2003, 82 (26) :4806-4808
[3]   Superior thermal conductivity of single-layer graphene [J].
Balandin, Alexander A. ;
Ghosh, Suchismita ;
Bao, Wenzhong ;
Calizo, Irene ;
Teweldebrhan, Desalegne ;
Miao, Feng ;
Lau, Chun Ning .
NANO LETTERS, 2008, 8 (03) :902-907
[4]  
Balandin AA, 2011, NAT MATER, V10, P569, DOI [10.1038/nmat3064, 10.1038/NMAT3064]
[5]   Influence of metal contacts and charge inhomogeneity on transport properties of graphene near the neutrality point [J].
Blake, P. ;
Yang, R. ;
Morozov, S. V. ;
Schedin, F. ;
Ponomarenko, L. A. ;
Zhukov, A. A. ;
Nair, R. R. ;
Grigorieva, I. V. ;
Novoselov, K. S. ;
Geim, A. K. .
SOLID STATE COMMUNICATIONS, 2009, 149 (27-28) :1068-1071
[6]   Preparation of ZnO nanorod arrays with tailored defect-related characteristics and their effect on the ethanol gas sensing performance [J].
Chang, C. M. ;
Hon, M. H. ;
Leu, I. C. .
SENSORS AND ACTUATORS B-CHEMICAL, 2010, 151 (01) :15-20
[7]   Zno nanostructures fabricated through a double-tube vapor-phase transport synthesis [J].
Chen, YX ;
Lewis, M ;
Zhou, WL .
JOURNAL OF CRYSTAL GROWTH, 2005, 282 (1-2) :85-93
[8]   Interpretation of Raman spectra of disordered and amorphous carbon [J].
Ferrari, AC ;
Robertson, J .
PHYSICAL REVIEW B, 2000, 61 (20) :14095-14107
[9]   The rise of graphene [J].
Geim, A. K. ;
Novoselov, K. S. .
NATURE MATERIALS, 2007, 6 (03) :183-191
[10]   Spatially resolved raman spectroscopy of single- and few-layer graphene [J].
Graf, D. ;
Molitor, F. ;
Ensslin, K. ;
Stampfer, C. ;
Jungen, A. ;
Hierold, C. ;
Wirtz, L. .
NANO LETTERS, 2007, 7 (02) :238-242