Kinetic studies on the reaction between benzyl/phenacyl chloride and N,N-dimethylaniline in acetone-water mixed solvents

被引：0

作者：

Nallu, M ^{[1
]}

Kanagadurgadevi, G ^{[1
]}

机构：

[1] Bharathidasan Univ, Dept Chem, Tiruchirappalli 620024, India

来源：

ASIAN JOURNAL OF CHEMISTRY | 2002年 / 14卷 / 3-4期

关键词：

kinetics; reaction; benzyl chloride; phenacyl chloride; N; N-dimethyl-aniline; solvents;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rate constants (k(1)) for the reaction between benzyl chloride (BC)/phenacyl chloride (PC) and N,N-dimethylaniline (DMA) have been determined conductometrically under pseudo-first-order conditions. Second order rate constants (k(2)) were evaluated in the usual way. The effect of electron withdrawing -CO- group alpha-to chlorine is not felt on the values of k(2(PC+DMA)). The marked effect of acetone-water solvent composition on the rate is known from correlation technique with log k(2(BC/PC+DMA)) with Grunwald-Winsteins (Y) and Kosowar (Z) of solvent polarity parameters.

引用

页码：1320 / 1324

页数：5