Synthesis, Crystal Structures and Properties of Two Heterometallic Complexes [Cu2M] (M = Cd, Mn) with a Novel Oxamato-bridged Ligand

被引：0

作者：

Zhang, Jie ^{[1
]}

Liu, Qing-Xia ^{[2
]}

Li, A-Hui ^{[2
]}

Liu, Bao-Lin ^{[2
,3
]}

Tao, Ruo-Jie ^{[2
]}

机构：

[1] Henan Univ, Key Lab Nat Med & Immunoengn, Kaifeng 475004, Peoples R China

[2] Henan Univ, Inst Mol & Crystal Engn, Coll Chem & Chem Engn, Kaifeng 475004, Peoples R China

[3] Nankai Univ, Key Lab Adv Energy Mat Chem, Tianjin 300071, Peoples R China

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2014年 / 69卷 / 01期

基金：

美国国家科学基金会;

关键词：

Copper(II); Manganese(II); Cadmium(II); Oxamato Bridging; Thiosemicarbazone; Crystal Structure; Antitumor Activity; COPPER(II) COMPLEXES; MAGNETIC-PROPERTIES; THIOSEMICARBAZONE;

D O I：

10.5560/ZNB.2014-3127

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel trinuclear oxamato-bridged thiosemicarbazone complexes, [Cu(obte)](2)Cd(DMF)(2) (2) and [Cu(obte)](2)Mn(DMF)(2) (3) (H(2)obte = N-(2-benzaldehyde) oxamic acid ethyl ester thiosemicarbazone (1); DMF = dimethylformamide), have been synthesized and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis (TGA) and single-crystal X-ray diffraction. Complexes 2 and 3 are isostructural, displaying a trinuclear structure. The luminescence properties of complexes 2 and 3 were investigated in the solid state at room temperature. The ligand 1 and its complex 2 have been evaluated for their antitumor activities against K562 cells.

引用

页码：49 / 54

页数：6

共 26 条

[1] Appended 1,2-naphthoquinones as anticancer agents 1: synthesis, structural, spectral and antitumor activities of ortho-naphthaquinone thiosemicarbazone and its transition metal complexes [J].

Afrasiabi, Z ;

Sinn, E ;

Chen, JN ;

Ma, YF ;

Rheingold, AL ;

Zakharov, LN ;

Rath, N ;

Padhye, S .

INORGANICA CHIMICA ACTA, 2004, 357 (01) :271-278

[2]

Ali MA, 2006, POLYHEDRON, V25, P3337

[3] The wide pharmacological versatility of semicarbazones, thiosemicarbazones and their metal complexes [J].

Beraldo, H ;

Gambino, D .

MINI-REVIEWS IN MEDICINAL CHEMISTRY, 2004, 4 (01) :31-39

[4] Linear trinuclear oximato-bridged complexes MnIII,IV;MII;MnIII,IV (M=Zn, Cu or Mn):: synthesis, structure, redox behaviour and magnetism [J].

Birkelbach, F ;

Weyhermuller, T ;

Lengen, M ;

Gerdan, M ;

Trautwein, AX ;

Wieghardt, K ;

Chaudhuri, P .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (23) :4529-4537

[5] Magneto-structural studies on heterobimetallic malonate-bridged MIIReIV complexes (M = Mn, Co, Ni and Cu) [J].

Cuevas, Alicia ;

Kremer, Carlos ;

Suescun, Leopoldo ;

Mombru, Alvaro W. ;

Lloret, Francesc ;

Julve, Miguel ;

Faus, Juan .

DALTON TRANSACTIONS, 2010, 39 (47) :11403-11411

[6] Synthesis and structure-activity relationship study of potent trypanocidal thio semicarbazone inhibitors of the trypanosomal cysteine protease cruzain [J].

Du, XH ;

Guo, C ;

Hansell, E ;

Doyle, PS ;

Caffrey, CR ;

Holler, TP ;

McKerrow, JH ;

Cohen, FE .

JOURNAL OF MEDICINAL CHEMISTRY, 2002, 45 (13) :2695-2707

[7] The preparation, characterization, crystal structure and biological activities of some copper(II) complexes of the 2-benzoylpyridine Schiff bases of S-methyl- and S-benzyldithiocarbazate [J].

Hossain, ME ;

Alam, MN ;

Begum, J ;

Ali, MA ;

Nazimuddin, M ;

Smith, FE ;

Hynes, RC .

INORGANICA CHIMICA ACTA, 1996, 249 (02) :207-213

[8] CHARACTERIZATION OF COPPER(II) COMPLEXES OF N4,N4-DISUBSTITUTED THIOSEMICARBAZONES OF 2-ACETYLPYRIDINE BY COMBINED EVALUATION OF ELECTRONIC AND ELECTRON-SPIN-RESONANCE PARAMETERS [J].

JAIN, SK ;

GARG, BS ;

BHOON, YK .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1986, 42 (09) :959-968

[9] Zintl phases for thermoelectric devices [J].

Kauzlarich, Susan M. ;

Brown, Shawna R. ;

Snyder, G. Jeffrey .

DALTON TRANSACTIONS, 2007, (21) :2099-2107

[10]

Kitchin JR, 2008, CHEM MODEL APPL THEO, V5, P150, DOI 10.1039/b608782p

← 1 2 3 →