Metal-metalloporphyrin frameworks: a resurging class of functional materials

被引：562
作者：
Gao, Wen-Yang [1 ]
Chrzanowski, Matthew [1 ]
Ma, Shengqian [1 ]
机构：
[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA
来源：
CHEMICAL SOCIETY REVIEWS | 2014年 / 43卷 / 16期
基金：
美国国家科学基金会;
关键词：
SUPRAMOLECULAR CRYSTAL-CHEMISTRY; MN-III-PORPHYRIN; ORGANIC FRAMEWORKS; COORDINATION POLYMERS; MICROPOROUS PORPHYRIN; HIGHLY EFFICIENT; ENERGY-TRANSFER; ASSEMBLY MODES; BUILDING-BLOCK; OPEN NETWORKS;
D O I：
10.1039/c4cs00001c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This review presents comprehensively recent progress in metal-metalloporphyrin frameworks (MMPFs) with an emphasis on versatile functionalities. Following a brief introduction of basic concepts and the potential virtues of MMPFs, we give a snapshot of the historical perspective of MMPFs since 1991. We then summarize four effective strategies implemented frequently to construct prototypal MMPFs. MMPFs represent a resurging class of promising functional materials, highlighted with diverse applications including guest-molecule adsorption and separation, catalysis, nano-thin films and light-harvesting.
引用
收藏
页码：5841 / 5866
页数：26
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