Reactive uptake coefficients for heterogeneous reaction of N2O5 with submicron aerosols of NaCl and natural sea salt

被引：52

作者：

Stewart, DJ ^{[1
]}

Griffiths, PT ^{[1
]}

Cox, RA ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Ctr Atmospher Sci, Cambridge CB2 1EW, England

来源：

ATMOSPHERIC CHEMISTRY AND PHYSICS | 2004年 / 4卷

关键词：

D O I：

10.5194/acp-4-1381-2004

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The kinetics of uptake of gaseous N2O5 on submicron aerosols containing NaCl and natural sea salt have been investigated in a flow reactor as a function of relative humidity (RH) in the range 30 - 80% at 295 +/- 2K and a total pressure of 1 bar. The measured uptake coefficients, gamma, were larger on the aerosols containing sea salt compared to those of pure NaCl, and in both cases increased with increasing RH. These observations are explained in terms of the variation in the size of the salt droplets, which leads to a limitation in the uptake rate into small particles. After correction for this effect the uptake coefficients are independent of relative humidity, and agree with those measured previously on larger droplets. A value of gamma = 0.025 is recommended for the reactive uptake coefficient for N2O5 on deliquesced sea salt droplets at 298 K and RH> 40%.

引用

页码：1381 / 1388

页数：8

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