Structure of nanoparticles in the ZrO2-Y2O3 system, as obtained under hydrothermal conditions

被引：5

作者：

Shuklina, A., I ^{[1
]}

Smirnov, A., V ^{[2
]}

Fedorov, B. A. ^{[2
]}

Kirillova, S. A. ^{[1
]}

Almjasheva, O., V ^{[3
]}

机构：

[1] St Petersburg State Electrotech Univ LETI, Ul Prof Popova 5, St Petersburg 197376, Russia

[2] ITMO Univ, Kronverksky Pr 49,Bldg A, St Petersburg 197101, Russia

[3] Ioffe Inst, Politekhnicheskaya St 26, St Petersburg 194021, Russia

来源：

NANOSYSTEMS-PHYSICS CHEMISTRY MATHEMATICS | 2020年 / 11卷 / 06期

基金：

俄罗斯科学基金会;

关键词：

nanocrystals; hydrothermal synthesis; solid solution; zirconia; PHASE-EQUILIBRIA; SOLID-SOLUTIONS; FLUORITE-STRUCTURE; ZIRCONIUM DIOXIDE; CRYSTAL-STRUCTURE; ZRO2; SURFACE; OXIDE; THERMODYNAMICS; NANOCRYSTALS;

D O I：

10.17586/2220-8054-2020-11-6-729-738

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

It is shown that monocrystalline nanoparticles with fluorite structure are formed in the ZrO2-Y2O3 system, under hydrothermal conditions. The limiting content of Y2O3 in the nanocrystals based on zirconium dioxide is 21.7-22.6 mol.%. Yttrium oxide not included in the structure forms an amorphous phase, which is stable even upon thermal treatment at 1000-1300 degrees C. It has been found that under hydrothermal conditions the structure of the nanocrystals based on ZrO2(Y2O3) solid solution includes water, its content depending on yttrium oxide concentration in the solid solution.

引用

页码：729 / 738

页数：10

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