Synthesis and electrical properties of novel oligomer semiconductors for organic field-effect transistors (OFETs): Asymmetrically end-capped acene-heteroacene conjugated oligomers

被引：25

作者：

Back, Jang Yeol ^{[1
,2
]}

Kim, Yebyeol ^{[3
]}

An, Tae Kyu ^{[3
]}

Kang, Moon Seong ^{[4
,5
]}

Kwon, Soon-Ki ^{[1
,2
]}

Park, Chan Eon ^{[3
]}

Kim, Yun-Hi ^{[4
,5
]}

机构：

[1] Gyeongsang Natl Univ, Sch Mat Sci & Engn, Jinju 660701, South Korea

[2] Gyeongsang Natl Univ, Res Inst Green Energy Convergence Technol REGET, Jinju 660701, South Korea

[3] Pohang Univ Sci & Technol, Polymer Res Inst, Dept Chem Engn, POSTECH Organ Elect Lab, Pohang 790784, South Korea

[4] Gyeongsang Natl Univ, Dept Chem, Jinju 660701, South Korea

[5] Gyeongsang Natl Univ, ERI, Jinju 660701, South Korea

来源：

DYES AND PIGMENTS | 2015年 / 112卷

关键词：

Organic field-effect transistor; Small molecule semiconductor; Solubility; Conjugated core modification; End-group; THIN-FILM TRANSISTORS; HIGH-PERFORMANCE; MOLECULAR-STRUCTURE; DESIGN; MOBILITY;

D O I：

10.1016/j.dyepig.2014.07.008

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Noble small molecules composed of an aromatic phenylene-trithiophene and naphthalene-trithiophene conjugated core were synthesized and examined for their property in p-type OFET devices. The phenylene and naphthalene moieties were combined with a trithiophene to introduce torsional structures into the conjugated core and improve the solubility compared with the solubility of the quaterthiophene core containing molecule. Although phenylene-trithiophene and naphthalene-trithiophene containing molecules showed lower mobilities (2.9 x 10(-3) and 1.04 x 10(-2) cm(2)/V, respectively) than quaterthiophene containing molecule (3.21 x 10(-2) cm(2)/V), they showed more film uniformity caused by improved solubility. The thermal stability, photochemical properties, and morphological characteristics were investigated using TGA, DSC, cyclic voltammetry, and XRD techniques. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：220 / 226

页数：7

共 27 条

[1] Organic semiconductors for solution-processable field-effect transistors (OFETs) [J].

Allard, Sybille ;

Forster, Michael ;

Souharce, Benjamin ;

Thiem, Heiko ;

Scherf, Ullrich .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (22) :4070-4098

[2] Synthesis and Transistor Properties of Asymmetric Oligothiophenes: Relationship between Molecular Structure and Device Performance [J].

An, Tae Kyu ;

Jang, Sang Hun ;

Kim, Seul-Ong ;

Jang, Jaeyoung ;

Hwang, Jihun ;

Cha, Hyojung ;

Noh, Young Ri ;

Yoon, Soon Byung ;

Yoon, Yong Jin ;

Kim, Lae Ho ;

Chung, Dae Sung ;

Kwon, Soon-Ki ;

Kim, Yun-Hi ;

Lee, Sang-Gyeong ;

Park, Chan Eon .

CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (42) :14052-14060

[3] Thin Film Morphology Control via a Mixed Solvent System for High-Performance Organic Thin Film Transistors [J].

An, Tae Kyu ;

Park, So-Min ;

Nam, Sooji ;

Hwang, Jaeyeong ;

Yoo, Seung-Jin ;

Lee, Min-Jung ;

Yun, Won Min ;

Jang, Jaeyoung ;

Cha, Hyojung ;

Hwang, Jihun ;

Park, Seonuk ;

Kim, Jiye ;

Chung, Dae Sung ;

Kim, Yun-Hi ;

Kwon, Soon-Ki ;

Park, Chan Eon .

SCIENCE OF ADVANCED MATERIALS, 2013, 5 (09) :1323-1327

[4] Molecular aggregation-performance relationship in the design of novel cyclohexylethynyl end-capped quaterthiophenes for solution-processed organic transistors [J].

An, Tae Kyu ;

Hahn, Seung-Hoon ;

Nam, Sooji ;

Cha, Hyojung ;

Rho, Yecheol ;

Chung, Dae Sung ;

Ree, Moonhor ;

Kang, Moon Seong ;

Kwon, Soon-Ki ;

Kim, Yun-Hi ;

Park, Chan Eon .

DYES AND PIGMENTS, 2013, 96 (03) :756-762

[5]

Atkins P., 2006, PHYS CHEM

[6] Field-effect transistors made from solution-processed organic semiconductors [J].

Brown, AR ;

Jarrett, CP ;

deLeeuw, DM ;

Matters, M .

SYNTHETIC METALS, 1997, 88 (01) :37-55

[7]

CHUNG DYF, 2012, APPL PHYS LETT, P101

[8]

Cowie JMG, 2008, POLYM CHEM PHYS MODE, P253

[9] Synthesis and characterization of diperfluorooctyl-substituted phenylene-thiophene oligomers as n-type semiconductors. Molecular structure-film microstructure-mobility relationships, organic field-effect transistors, and transistor nonvolatile memory elements [J].

Facchetti, A ;

Letizia, J ;

Yoon, MH ;

Mushrush, M ;

Katz, HE ;

Marks, TJ .

CHEMISTRY OF MATERIALS, 2004, 16 (23) :4715-4727

[10] Dithieno[2,3-d;2′,3′-d′]benzo[1,2-b;4,5-b′]dithiophene (DTBDT) as Semiconductor for High-Performance, Solution-Processed Organic Field-Effect Transistors [J].

Gao, Peng ;

Beckmann, Dirk ;

Tsao, Hoi Nok ;

Feng, Xinliang ;

Enkelmann, Volker ;

Baumgarten, Martin ;

Pisula, Wojciech ;

Muellen, Klaus .

ADVANCED MATERIALS, 2009, 21 (02) :213-+

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