Excellent photoluminescence and cathodoluminescence properties in Eu3+-activated Sr2LaNbO6 materials for multifunctional applications

被引:163
作者
Hua, Yongbin [1 ]
Ran, Weiguang [2 ]
Yu, Jae Su [1 ]
机构
[1] Kyung Hee Univ, Inst Wearable Convergence Elect, Dept Elect & Informat Convergence Engn, Yongin 17104, Gyeonggi Do, South Korea
[2] Qufu Normal Univ, Dept Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China
基金
新加坡国家研究基金会;
关键词
Color purity; Thermal stability; LED; PDMS film; FEDs; RED-EMITTING PHOSPHORS; LUMINESCENCE ENHANCEMENT; HIGH-EFFICIENCY; ENERGY-TRANSFER; GREEN PHOSPHOR; COLOR PURITY; EMISSION; STABILITY; EXCITATION; ORANGE;
D O I
10.1016/j.cej.2020.127154
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Single Eu3+-activated Sr2LaNbO6 (SLN) phosphors with double-perovskite structure were successfully synthesized and their photo/cathodoluminescence properties were investigated in detail. The optimal doping concentration was confirmed to be about 0.3 mol while the concentration quenching was dominated by the dipole-dipole interaction. The optimum SLN:0.3Eu(3+) phosphor exhibited good photoluminescence emission intensity, color purity, thermal stability, and quantum yield. With the help of the Judd-Oflet theory, Eu3+ ions would possess the stronger symmetry sites in SLN host lattice. Besides, the packaged red and white lighting emitting diodes (LEDs) based on optimum sample were fabricated. Particularly, the packaged white LED device displayed good color rendering index value of 86.89 and correlated color temperature value of 4835 K. Moreover, the novel LED structure based on the SLN:0.3Eu(3+)-polydimethylsiloxane film having stable physicochemical structure was prepared and emitted a strong red light. Eventually, the strong cathodoluminescence intensity with large electron penetration depth was provided. These above results imply that SLN:Eu3+ phosphors with excellent photo/cathodoluminescence properties could be promised for multifunctional applications.
引用
收藏
页数:15
相关论文
共 83 条
[1]   Photoluminescence and cathodoluminescence properties of novel rare-earth free narrow-band bright green-emitting ZnB2O4:Mn2+ phosphor for LEDs and FEDs [J].
Chen, Hang ;
Wang, Yuhua .
CHEMICAL ENGINEERING JOURNAL, 2019, 361 :314-321
[2]   Eu3+-Activated NaGdF4 Nanorods for Near-Ultraviolet Light-Triggered Indoor Illumination [J].
Du, Peng ;
Ran, Weiguang ;
Hou, Yafei ;
Luo, Laihui ;
Li, Weiping .
ACS APPLIED NANO MATERIALS, 2019, 2 (07) :4275-+
[3]   Synthesis and luminescent properties of Eu3+-activated Na0.5Gd0.5MoO4: A strong red-emitting phosphor for LED and FED applications [J].
Du, Peng ;
Yu, Jae Su .
JOURNAL OF LUMINESCENCE, 2016, 179 :451-456
[4]   Upconversion emission, cathodoluminescence and temperature sensing behaviors of Yb3+ ions sensitized NaY(WO4)2:Er3+ phosphors [J].
Du, Peng ;
Luo, Laihui ;
Yu, Jae Su .
CERAMICS INTERNATIONAL, 2016, 42 (05) :5635-5641
[5]   Biomimetic diodon-skin nanothorn polymer antireflection film for solar cell applications [J].
Fang, Chaolong ;
Yang, Zhitong ;
Zhang, Jian ;
Zhuang, Youyi ;
Liu, Siyuan ;
He, Xin ;
Zhang, Yaoju .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2020, 206
[6]   Synthesis, structure, and luminescence properties of a novel double-perovskite Sr2LaNbO6:Mn4+ phosphor [J].
Fu, Anjie ;
Guan, Anxiang ;
Yu, Dongyan ;
Xia, Siyu ;
Gao, Fangfang ;
Zhang, Xiaoshan ;
Zhou, Liya ;
Li, Yinghao ;
Li, Rongguan .
MATERIALS RESEARCH BULLETIN, 2017, 88 :258-265
[7]  
Fu J, 2020, CERAM INT, V46, P20277, DOI [10.1016/j.ceramint.2020.05.114, 10.1016/j.ceramint.2020.05.110]
[8]  
Geng W., 2018, J AM CERAM SOC, V101, P10
[9]   In Situ Inkjet Printing of the Perovskite Single-Crystal Array-Embedded Polydimethylsiloxane Film for Wearable Light-Emitting Devices [J].
Gu, Zhenkun ;
Huang, Zhandong ;
Hu, Xiaotian ;
Wang, Ying ;
Li, Lihong ;
Li, Mingzhu ;
Song, Yanlin .
ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (19) :22157-22162
[10]   Efficiency enhancement of silicon solar cells covered by GeO2-PbO glasses doped with Eu3+ and TiO2 nanoparticles [J].
Gunji, R. M. ;
Mattos, G. R. S. ;
Bordon, C. D. S. ;
Gomez-Malagon, L. A. ;
Kassab, L. R. P. .
JOURNAL OF LUMINESCENCE, 2020, 223