Thermodynamic properties of refrigerants from SM sound velocity-based equation of state

被引:5
作者
Alavianmehr, Mohammad Mehdi [1 ]
Behnejad, Hassan [2 ]
Jahangiri, Soran [2 ]
Hosseini, Sayed Mostafa [3 ]
机构
[1] Shiraz Univ Technol, Dept Chem, Shiraz 71555313, Iran
[2] Univ Tehran, Dept Chem, Fac Sci, Tehran, Iran
[3] Shiraz Univ, Dept Chem, Shiraz 71454, Iran
关键词
corresponding states; equation of state; refrigerants; speed of sound; statistical mechanic; thermodynamic properties; THERMOPHYSICAL PROPERTIES; GASEOUS REFRIGERANTS; SPEED; DENSITY; FLUID; PREDICTION; MIXTURES; MODEL;
D O I
10.1080/00319104.2013.852477
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The present work aims to predict thermodynamic properties of several refrigerants using the Song and Mason (SM) equation of state (EOS). The calculations of thermodynamic properties including enthalpy, entropy, internal energy, isobaric and isochoric heat capacities, and speed of sound of these fluids have been carried out along saturation curve and in the gas phase region. The accuracy of calculated saturated density of studied refrigerant fluids was of the order of +/- 3%. Generally, our calculations led to the overall average absolute deviation (AAD in %) of calculated internal energy, enthalpy, entropy, isobaric and isochoric heat capacities, and speed of sound equal to 0.62%, 0.58%, 0.53%, 1.4%, 1.06% and 0.48%, respectively. Also, our calculations on the enthalpy, entropy, isobaric and isochoric heat capacities, and speed of sound at compressed states led to the AADs equal to 1.00%, 0.53%, 1.42%, 1.62% and 0.55%, respectively.
引用
收藏
页码:546 / 555
页数:10
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