Carbazole-based enamine: Low-cost and efficient hole transporting material for perovskite solar cells

被引：101

作者：

Daskeviciene, Maryte ^{[1
]}

Paek, Sanghyun ^{[2
]}

Wang, Zhiping ^{[3
]}

Malinauskas, Tadas ^{[1
]}

Jokubauskaite, Gabriele ^{[1
]}

Rakstys, Kasparas ^{[2
]}

Cho, Kyung Taek ^{[2
]}

Magomedov, Artiom ^{[1
]}

Jankauskas, Vygintas ^{[4
]}

Ahmad, Shahzada ^{[5
]}

Snaith, Henry J. ^{[3
]}

Getautis, Vytautas ^{[1
]}

Nazeeruddin, Mohammad Khaja ^{[2
]}

机构：

[1] Kaunas Univ Technol, Dept Organ Chem, Radvilenu Pl 19, LT-50254 Kaunas, Lithuania

[2] Ecole Polytech Fed Lausanne, Inst Chem Sci & Engn, Grp Mol Engn Funct Mat, CH-1951 Sion, Switzerland

[3] Univ Oxford, Dept Phys, Clarendon Lab, Parks Rd, Oxford OX1 3PU, England

[4] Vilnius Univ, Dept Solid State Elect, Sauletekio 9, LT-10222 Vilnius, Lithuania

[5] Abengoa Res, Energia Solar 1, Seville 41014, Spain

来源：

NANO ENERGY | 2017年 / 32卷

基金：

英国工程与自然科学研究理事会;

关键词：

Aldehydes; Carbazole; Enamine; Perovskite solar cell; Semiconductors;

D O I：

10.1016/j.nanoen.2017.01.015

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A simple carbazole-based conjugated enamine V950 was synthesized, fully characterized and incorporated into a perovskite solar cell, which displayed high power conversion efficiency close to 18%. The investigated hole transporting material was synthesized via an extremely simple route (one step, no expensive catalysts, no column chromatography or sublimation purification) from commercially available and relatively inexpensive starting reagents, resulting in more than one order of magnitude lower cost of the final product compared to the commercial 2,2', 7,7'-tetrakis( N, N-di-p-methoxy-phenylamine)-9-9'-spirobifluorene (spiro-OMeTAD). This material promises to be a viable p-type organic charge conductor to be employed in the scale-up and manufacturing of perovskite solar modules.

引用

页码：551 / 557

页数：7

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