In situ synthesis of Co3O4/Cu electrode and its high performance for lithium-ion batteries

被引:11
作者
Wang, Beibei [1 ]
Wang, Gang [2 ]
Wang, Hui [1 ]
机构
[1] NW Univ Xian, Coll Chem & Mat Sci, Minist Educ, Key Lab Synthet & Nat Funct Mol Chem, Xian 710069, Peoples R China
[2] NW Univ Xian, Inst Photon & Photon Technol, Natl Photoelectr Technol & Funct Mat & Applicat, Natl Key Lab Photoelectr Technol & Funct Mat Cult, Xian 710069, Peoples R China
基金
中国国家自然科学基金;
关键词
Cobalt oxide array; Crystal structure; Functional; Lithium ion batteries; ANODE MATERIALS;
D O I
10.1016/j.matlet.2014.02.004
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this paper, we report the growth of CO3O4 micro-rod arrays on Cu substrate by a modified hydrothermal method. The obtained Co3O4/Cu shows that the formed CO3O4 micro-rods on Cu foil are 1-2 mu m in diameter and 25 mu m in length. When evaluated as electrode materials for lithium-ion batteries, the specific capacity of CO3O4/Cu materials remains over 0.8 mA h mg(-1) after 50 cycles at 0.1 C. The superior electrochemical performance of the CO3O4/Cu electrode may be attributed to the close contact of CO3O4 micro-rod arrays on Cu substrate and the extra space between the neighboring arrays, which provide fast pathways and reduce volume expansion. (c) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:186 / 189
页数:4
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