Molecular conductors with 8,8′-diiodo cobalt bis(dicarbollide) anion

被引：45
|
作者：
Kazheva, Olga N. [2 ]
Alexandrov, Grigorii G. [3 ]
Kravchenko, Andrey V. [4 ]
Starodub, Vladimir A. [4 ,5 ]
Lobanova, Irina A. [1 ]
Sivaev, Igor B. [1 ]
Bregadze, Vladimir I. [1 ]
Titov, Lev V. [2 ]
Buravov, Lev I. [2 ]
Dyachenko, Oleg A. [2 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
[2] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Region, Russia
[3] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia
[4] Kharkov Natl Univ, UA-61077 Kharkov, Ukraine
[5] Jan Kochanowski Univ Humanities & Sci, Inst Chem, PL-25020 Kielce, Poland
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2009年 / 694卷 / 15期
基金：
俄罗斯基础研究基金会;
关键词：
Molecular conductors; 8,8 '-Diiodo-3,3 '-cobalt bis(1,2-dicarbollide); Tetrathiafulvalenium; Bis( methylenedithio)-tetrathiafulvalenium; Bis(ethylenedithio)-tetrathiafulvalenium; Crystal structure; CHARGE-TRANSFER; PHYSICAL-PROPERTIES; FULVALENIUM SALTS; ELECTRON-DONORS; TTF; DERIVATIVES; METALLABORANES; CHEMISTRY; IRON;
D O I：
10.1016/j.jorganchem.2009.03.035
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New molecular conductors on the base of 8,8'-diiodo cobalt bis(dicarbollide) anion (TTF)[8,8'-I-2-3,3'-Co(1,2-C2B9H10)(2)] (1), (BMDT-TTF)(4)[8,8'-I-2-3,3'-Co(1,2-C2B9H10)(2)] (2) and (BEDT-TTF)(2)[8,8'-I-2-3,3'-Co(1,2-C2B9H10)(2)] (3) were synthesized and their crystal structures and electrical conductivities were determined. All the radical cation salts prepared were found to be semiconductors. Some regularities in the crystal structures of the TTF-based radical cation salts with bis(dicarbollide) complexes of transition metals are discussed. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：2336 / 2342
页数：7
相关论文
共 50 条
  • [1] First molecular conductors with 8,8′-dibromo cobalt bis(dicarbollide) anion
    Kazheva, Olga
    Alexandrov, Grigorii
    Kravchenko, Andrey
    Starodub, Vladimir
    Lobanova, Irina
    Sivaev, Igor
    Bregadze, Vladimir
    Buravov, Lev
    Dyachenko, Oleg
    SOLID STATE SCIENCES, 2008, 10 (12) : 1734 - 1739
  • [2] Molecular Conductors with a 8-Hydroxy cobalt Bis(dicarbollide) Anion
    Kazheva, Olga N.
    Alexandrov, Grigorii G.
    Kravchenko, Andrey V.
    Kosenko, Irina D.
    Lobanova, Irina A.
    Sivaev, Igor B.
    Filippov, Oleg A.
    Shubina, Elena S.
    Bregadze, Vladimir I.
    Starodub, Vladimir A.
    Titov, Lev V.
    Buravov, Lev I.
    Dyachenko, Oleg A.
    INORGANIC CHEMISTRY, 2011, 50 (02) : 444 - 450
  • [3] New molecular conductors with cobalt bis(dicarbollide) anion
    Kazheva, Olga
    Chekhlov, Anatolii
    Starodub, Vladimir
    Dyachenko, Oleg
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2006, 62 : S295 - S295
  • [4] Synthesis of 8-alkoxy and 8,8′-dialkoxy derivatives of cobalt bis(dicarbollide)
    Stogniy, Marina Yu.
    Suponitsky, Kyrill Yu.
    Chizhov, Alexander O.
    Sivaev, Igor B.
    Bregadze, Vladimir I.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2018, 865 : 138 - 144
  • [5] Rotational conformation of 8,8′-dihalogenated derivatives of cobalt bis(dicarbollide) in solution
    I. B. Sivaev
    I. D. Kosenko
    Russian Chemical Bulletin, 2021, 70 : 753 - 756
  • [6] Rotational conformation of 8,8′-dihalogenated derivatives of cobalt bis(dicarbollide) in solution
    Sivaev, I. B.
    Kosenko, I. D.
    RUSSIAN CHEMICAL BULLETIN, 2021, 70 (04) : 753 - 756
  • [7] New electroconducting radical cation salts based on BEDT-TTF with 8,8′-dibromo cobalt bis(dicarbollide) anion
    Kazheva, Olga
    Alexandrov, Grigorii
    Kravchenko, Andrey
    Starodub, Vladimir
    Lobanova, Irina
    Sivaev, Igor
    Bregadze, Vladimir
    Titov, Lev
    Dyachenko, Oleg
    SMART MATERIALS & MICRO/NANOSYSTEMS, 2009, 54 : 331 - 336
  • [8] Molecular conductors with anti-7,7′:8,8′-bis(dithio)bis (7,8-dicarbaundecaborate) anion
    Kravchenko, Andrey V.
    Timofeev, Sergey V.
    Kazheva, Olga N.
    Alexandrov, Grigorii G.
    Sivaev, Igor B.
    Bregadze, Vladimir I.
    Starodub, Vladimir A.
    Buravov, Lev I.
    Dyachenko, Oleg A.
    INORGANIC CHEMISTRY COMMUNICATIONS, 2013, 33 : 109 - 113
  • [9] Bis(dicarbollide) Complexes of Transition Metals as a Platform for Molecular Switches. Study of Complexation of 8,8′-Bis(methylsulfanyl) Derivatives of Cobalt and Iron Bis(dicarbollides)
    Anufriev, Sergey A.
    Timofeev, Sergey, V
    Anisimov, Alexei A.
    Suponitsky, Kyrill Yu
    Sivaev, Igor B.
    MOLECULES, 2020, 25 (23):
  • [10] New molecular conductors with halogen substituted cobalt bis(dicarbollide) anions
    Dyachenko, Oleg
    Kazheva, Olga
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2011, 67 : C638 - C639
12345