Synthesis, characterization and molecular structure of two Ru-4 clusters with beta-alkylstyrene ligands

被引：4

作者：

Gaede, PE ^{[1
]}

Parsons, S ^{[1
]}

Johnson, BFG ^{[1
]}

机构：

[1] UNIV EDINBURGH, DEPT CHEM, EDINBURGH EH9 3JJ, MIDLOTHIAN, SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 24期

关键词：

D O I：

10.1039/dt9960004629

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ruthenium clusters [Ru-4(CO)(10)(C9H10)] 1 and [Ru-4(CO)(10)(C10H12)] 2 have been obtained together with other products from the reaction of [Ru-3(CO)(12)] with allylbenzene or 4-phenylbut-1-ene respectively in octane under reflux. Their molecular structures have been elucidated by single-crystal X-ray crystallography. That of 1 exhibits two co-ordination isomers in the solid state for the facial bonded ligand. Force-field calculations on each isomer revealed a small energy difference between them.

引用

页码：4629 / 4632

页数：4

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