New aromatic pentafluoro-λ6-sulfanyl (SF5) derivatives, m-SF5(CF2)2C6H4X:: (X=N3, Br, OC(O)CH=CH2, CH=CH2)

被引：9

作者：

Winter, RW ^{[1
]}

Winner, SW ^{[1
]}

Preston, DA ^{[1
]}

Mohtasham, J ^{[1
]}

Smith, JA ^{[1
]}

Gard, GL ^{[1
]}

机构：

[1] Portland State Univ, Dept Chem, Portland, OR 97207 USA

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2002年 / 115卷 / 01期

基金：

美国国家科学基金会;

关键词：

pentafluorothiofluoroalkyl benzene derivatives; SF5; acrylate/stryrene monomers and polymers;

D O I：

10.1016/S0022-1139(02)00059-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Preparation of the following new m-SF5CF2CF2C6H4X derivatives has been achieved: X = N-3(2), Br(3), OC(O)CH=CH2(4), CH=CH2(5). The compounds were characterized by their respective IR, NMR, mass spectra (MS) and high resolution mass spectrometry (HRMS). An improved yield of SF5(CF2)(2)C6H5 (1) is also reported along with the synthesis of the polyacrylate (6) and polystyrene (7) from their respective monomers. (C) 2002 Published by Elsevier Science B.V.

引用

页码：101 / 105

页数：5

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